An unexpected reaction of cinobufagin analogues in the presence of PPh3/I-2

doi:10.1007/s00706-020-02577-7

	An unexpected reaction of cinobufagin analogues in the presence of PPh3/I-2
	Zhou, Yang 1,2; Zhang, Yanzhi 3; Chen, Xubing 3; Hou, Jinjun 1,2; Long, Huali 1,2; Zhang, Zijia 1,2; Guo, Dean 1,2; Lei, Min 1,2; Wu, Wanying 1,2
刊名	MONATSHEFTE FUR CHEMIE
	2020-04-01
卷号	151 期号:4 页码:617-623
关键词	Cinobufagin Bufalene PPh3/I-2 Cyclopenta-1 3-Diene Natural product
ISSN号	0026-9247
DOI	10.1007/s00706-020-02577-7
通讯作者	Lei, Min(mlei@simm.ac.cn) ; Wu, Wanying(wanyingwu@simm.ac.cn)
英文摘要	An unexpected reaction of cinobufagin analogues in the presence of PPh3/I-2 in EtOAc at room temperature to obtain diene compounds has been described. The whole process is carried out under mild conditions and the desired products are formed in good yields. It provides a simple, effective, and novel reaction method for the synthesis of diene compounds from corresponding substrates. [GRAPHICS] .
资助项目	Special Fund for Strategic Pilot Technology Chinese Academy of Sciences[XDA12020379] ; National Natural Science Foundation of China[81973455]
WOS关键词	DERIVATIVES
WOS研究方向	Chemistry
语种	英语
出版者	SPRINGER WIEN
WOS记录号	WOS:000529487400001
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/280506]
专题	中国科学院上海药物研究所
通讯作者	Lei, Min; Wu, Wanying
作者单位	1.Chinese Acad Sci, Shanghai Res Ctr Modernizat Tradit Chinese Med, Shanghai Inst Mat Med, Natl Engn Lab TCM Standardizat Technol, Shanghai 201203, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Dali Univ, Coll Pharm, Dali 671000, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Yang,Zhang, Yanzhi,Chen, Xubing,et al. An unexpected reaction of cinobufagin analogues in the presence of PPh3/I-2[J]. MONATSHEFTE FUR CHEMIE,2020,151(4):617-623.
APA	Zhou, Yang.,Zhang, Yanzhi.,Chen, Xubing.,Hou, Jinjun.,Long, Huali.,...&Wu, Wanying.(2020).An unexpected reaction of cinobufagin analogues in the presence of PPh3/I-2.MONATSHEFTE FUR CHEMIE,151(4),617-623.
MLA	Zhou, Yang,et al."An unexpected reaction of cinobufagin analogues in the presence of PPh3/I-2".MONATSHEFTE FUR CHEMIE 151.4(2020):617-623.