In-situ synthesis of nanocrystalline TiC powders, nanorods, and nanosheets in molten salt by disproportionation reaction of Ti(II) species

doi:10.1016/j.jmst.2019.08.017

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	In-situ synthesis of nanocrystalline TiC powders, nanorods, and nanosheets in molten salt by disproportionation reaction of Ti(II) species
	Yang, Lingxu 1,2; Wang, Ying 1,2; Liu, Ruijia 1,2; Liu, Huijun 2,3; Zhang, Xue 2; Zeng, Chaoliu 2,3; Fu, Chao 3
刊名	JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
	2020-01-15
卷号	37 页码:173-180
关键词	Titanium carbide Nanocrystalline Nanorod Nanosheet Disproportionation Molten salt
ISSN号	1005-0302
DOI	10.1016/j.jmst.2019.08.017
通讯作者	Liu, Huijun(liuhj@imr.ac.cn)
英文摘要	A high-efficiency method is developed to in-situ synthesize nanocrystalline TiC powders, nanorods, and nanosheets by using equimolar ratio of Ti powder and acetylene black, multiwalled carbon nanotubes (MWCNTs), and graphene, respectively, as precursor in eutectic NaCl-KCl molten salt at 800-900 degrees C for 2-3 h. Higher temperature and longer duration are more beneficial for TiC preparation. In addition, mechanism of TiC formation was investigated by linear scan voltammetry. Results indicate that nanocrystalline TiC is in-situ synthesized by reaction between Ti atoms, which come from disproportionation reaction of Ti(II) species in the molten salt, and C atoms on the surface of carbon sources. (C) 2019 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
资助项目	National Natural Science Foundation of China[51671204] ; National Natural Science Foundation of China[51501205]
WOS研究方向	Materials Science ; Metallurgy & Metallurgical Engineering
语种	英语
出版者	JOURNAL MATER SCI TECHNOL
WOS记录号	WOS:000503163100021
资助机构	National Natural Science Foundation of China
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/136412]
专题	金属研究所_中国科学院金属研究所
通讯作者	Liu, Huijun
作者单位	1.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Lab Corros & Protect, Shenyang 110016, Liaoning, Peoples R China 3.Songshan Lake Mat Lab, Dongguan 523808, Peoples R China
推荐引用方式 GB/T 7714	Yang, Lingxu,Wang, Ying,Liu, Ruijia,et al. In-situ synthesis of nanocrystalline TiC powders, nanorods, and nanosheets in molten salt by disproportionation reaction of Ti(II) species[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2020,37:173-180.
APA	Yang, Lingxu.,Wang, Ying.,Liu, Ruijia.,Liu, Huijun.,Zhang, Xue.,...&Fu, Chao.(2020).In-situ synthesis of nanocrystalline TiC powders, nanorods, and nanosheets in molten salt by disproportionation reaction of Ti(II) species.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,37,173-180.
MLA	Yang, Lingxu,et al."In-situ synthesis of nanocrystalline TiC powders, nanorods, and nanosheets in molten salt by disproportionation reaction of Ti(II) species".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 37(2020):173-180.