Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO)

doi:10.1016/j.cej.2019.01.019

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	Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO)
	Ou, Xiaoxia 3; Pilitsis, Fotios 3; Jiao, Yilai 1,3; Zhang, Yong 4; Xu, Shaojun 3; Jennings, Martin 2; Yang, Yi 4; Taylor, S. F. Rebecca 3; Garforth, Arthur 3; Zhang, Huiping 4
刊名	CHEMICAL ENGINEERING JOURNAL
	2019-04-15
卷号	362 页码:53-62
关键词	SiC foam Structured catalyst Chemical vapour deposition (CVD) Catalytic wet peroxide oxidation (CWPO) Macromixing
ISSN号	1385-8947
DOI	10.1016/j.cej.2019.01.019
通讯作者	Hardacre, Christopher(c.hardacre@manchester.ac.uk) ; Yan, Ying(yingyan@scut.edu.cn) ; Fan, Xiaolei(xiaolei.fan@manchester.ac.uk)
英文摘要	Structured Fe-ZSM-5 zeolite supported on silicon carbide (SiC) foam catalyst was develop and applied as the packed foam bed catalytic reactor (FBCR) to the liquid phase catalytic wet peroxide oxidation (CWPO) of phenol under flow conditions. Fe catalysts were uniformly incorporated into ZSM-5 coatings using chemical vapour deposition (CVD). Fluid flow analysis of FBCR was performed by varying liquid flow rate, showing the transition of reactor type from the plug flow reactor to the continuous stirred tank reactor at about 1 ml min(-1). Systematic investigation of CWPO within Fe-ZSM-5/SiC FBCRs identified the optimum condition of operating the FBCR (80 mm bed length) as at 60 degrees C and 1 ml min(-1) with the turnover frequency (TOF) of 95 h(-1) for phenol degradation (apparent activation energy = 3.4 kJ mol(-1)) and total organic carbon (TOC) conversion of 45.5%. It was believed that the enhanced macromixing promoted by cellular foam supports was accountable for the observed catalytic performance. The longevity of FBCR under flow conditions was also assessed, showing its good stability over 24 h, as well as the potential for practical adoption.
资助项目	Engineering and Physical Sciences Research Council[EP/R000670/1] ; Guangzhou Elite Project scholarship ; CEAS postgraduate research scholarship, The University of Manchester ; Liaoning Provincial Natural Science Foundation of China[20180510012] ; China Scholarship Council (CSC)[201604910181] ; Higher Education Innovation Funded 'Knowledge and Innovation Hub for Environmental Sustainability' at The University of Manchester ; National Natural Science Foundation of China[21776106] ; National Natural Science Foundation of China[21376101] ; Pearl River S&T Nova Program of Guangzhou[201610010171]
WOS研究方向	Engineering
语种	英语
出版者	ELSEVIER SCIENCE SA
WOS记录号	WOS:000457863500006
资助机构	Engineering and Physical Sciences Research Council ; Guangzhou Elite Project scholarship ; CEAS postgraduate research scholarship, The University of Manchester ; Liaoning Provincial Natural Science Foundation of China ; China Scholarship Council (CSC) ; Higher Education Innovation Funded 'Knowledge and Innovation Hub for Environmental Sustainability' at The University of Manchester ; National Natural Science Foundation of China ; Pearl River S&T Nova Program of Guangzhou
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/131499]
专题	金属研究所_中国科学院金属研究所
通讯作者	Hardacre, Christopher; Yan, Ying; Fan, Xiaolei
作者单位	1.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Univ Manchester, Sch Chem, Oxford Rd, Manchester, Lancs, England 3.Univ Manchester, Sch Chem Engn & Analyt Sci, Oxford Rd, Manchester, Lancs, England 4.South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Ou, Xiaoxia,Pilitsis, Fotios,Jiao, Yilai,et al. Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO)[J]. CHEMICAL ENGINEERING JOURNAL,2019,362:53-62.
APA	Ou, Xiaoxia.,Pilitsis, Fotios.,Jiao, Yilai.,Zhang, Yong.,Xu, Shaojun.,...&Fan, Xiaolei.(2019).Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO).CHEMICAL ENGINEERING JOURNAL,362,53-62.
MLA	Ou, Xiaoxia,et al."Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO)".CHEMICAL ENGINEERING JOURNAL 362(2019):53-62.