Separation and detection of trace atrazine from seawater using dummy-template molecularly imprinted solid-phase extraction followed by high-performance liquid chromatography

doi:10.1016/j.marpolbul.2019.110502

CORC > 海洋研究所 > 中国科学院海洋研究所 > 海洋生态与环境科学重点实验室

	Separation and detection of trace atrazine from seawater using dummy-template molecularly imprinted solid-phase extraction followed by high-performance liquid chromatography
	Chen, Jianlei 3; Zhao, Weihong 1,2; Tan, Liju 3; Wang, Junfu 3; Li, Huiping 3; Wang, Jiangtao 3
刊名	MARINE POLLUTION BULLETIN
	2019-12-01
卷号	149 页码:6
关键词	Atrazine Cyromazine Dummy-template Molecularly imprinted solid-phase extraction Seawater
ISSN号	0025-326X
DOI	10.1016/j.marpolbul.2019.110502
通讯作者	Zhao, Weihong(whzhao@qdio.ac.cn) ; Wang, Jiangtao(jtwang@ouc.edu.cn)
英文摘要	A novel sample pretreatment strategy for separation and detection of atrazine from seawater was established with molecular imprinting solid-phase extraction (MISPE). Cyromazine was used as dummy-template based on computational analysis to synthesize dummy-template molecularly imprinted polymers (DMIPs) as sorbent of MISPE for atrazine analysis. The DMIPs were irregular loose porous layered structure characterized by scanning electron microscopy and showed higher binding capacity than non-imprinted polymers through adsorption experiments. An offline MISPE procedure using DMIPs as sorbent coupled with high-performance liquid chromatograph was developed for separation and purification of atrazine from seawater samples. The recoveries of atrazine in the spiked seawater samples ranged from 86.7% to 98.6%, and the relative standard deviation was less than 4.07% (n = 3) under optimal conditions indicating that the proposed method was suitable for the detection of trace residual atrazine in seawater. In addition, no atrazine was detected in three seawater samples from Jiaozhou bay, China.
资助项目	National Natural Science Foundation of China[41876078] ; Public Science and Technology Research Funds Projects of Ocean[201505034] ; Fundamental Research Funds for The Central Universities[201713059]
WOS研究方向	Environmental Sciences & Ecology ; Marine & Freshwater Biology
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000501387300112
内容类型	期刊论文
源URL	[http://ir.qdio.ac.cn/handle/337002/163891]
专题	海洋研究所_海洋生态与环境科学重点实验室
通讯作者	Zhao, Weihong; Wang, Jiangtao
作者单位	1.Univ Chinese Acad Sci, Beijing, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Ecol & Environm Sci, Qingdao 266071, Shandong, Peoples R China 3.Ocean Univ China, Key Lab Marine Chem Theory & Technol, Minist Educ, Qingdao 266100, Shandong, Peoples R China
推荐引用方式 GB/T 7714	Chen, Jianlei,Zhao, Weihong,Tan, Liju,et al. Separation and detection of trace atrazine from seawater using dummy-template molecularly imprinted solid-phase extraction followed by high-performance liquid chromatography[J]. MARINE POLLUTION BULLETIN,2019,149:6.
APA	Chen, Jianlei,Zhao, Weihong,Tan, Liju,Wang, Junfu,Li, Huiping,&Wang, Jiangtao.(2019).Separation and detection of trace atrazine from seawater using dummy-template molecularly imprinted solid-phase extraction followed by high-performance liquid chromatography.MARINE POLLUTION BULLETIN,149,6.
MLA	Chen, Jianlei,et al."Separation and detection of trace atrazine from seawater using dummy-template molecularly imprinted solid-phase extraction followed by high-performance liquid chromatography".MARINE POLLUTION BULLETIN 149(2019):6.