Effective Surface Treatment for High-Performance Inverted CsPbI2Br Perovskite Solar Cells with Efficiency of 15.92%

doi:10.1007/s40820-020-00509-y

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	Effective Surface Treatment for High-Performance Inverted CsPbI2Br Perovskite Solar Cells with Efficiency of 15.92%
	Fu, Sheng ; Li, Xiaodong ; Wan, Li ; Zhang, Wenxiao ; Song, Weijie ; Fang, Junfeng
刊名	NANO-MICRO LETTERS
	2020
卷号	12 期号:1
关键词	STABILITY TRANSPORT STRATEGY CATION LAYER
DOI	10.1007/s40820-020-00509-y
英文摘要	Developing high-efficiency and stable inverted CsPbI2Br perovskite solar cells is vitally urgent for their unique advantages of removing adverse dopants and compatible process with tandem cells in comparison with the regular. However, relatively low opening circuit voltage (V-oc) and limited moisture stability have lagged their progress far from the regular. Here, we propose an effective surface treatment strategy with high-temperature FABr treatment to address these issues. The induced ions exchange can not only adjust energy level, but also gift effective passivation. Meanwhile, the gradient distribution of FA(+)can accelerate the carriers transport to further suppress bulk recombination. Besides, the Br-rich surface and FA(+)substitution can isolate moisture erosions. As a result, the optimized devices show champion efficiency of 15.92% withV(oc)of 1.223 V. In addition, the tolerance of humidity and operation get significant promotion: maintaining 91.7% efficiency after aged at RH 20% ambient condition for 1300 h and 81.8% via maximum power point tracking at 45 degrees C for 500 h in N-2. Furthermore, the unpackaged devices realize the rare reported air operational stability and, respectively, remain almost efficiency (98.9%) after operated under RH 35% for 600 min and 91.2% under RH 50% for 300 min. Graphic
学科主题	Science & Technology - Other Topics ; Materials Science ; Physics
内容类型	期刊论文
源URL	[http://ir.nimte.ac.cn/handle/174433/20572]
专题	2020专题
作者单位	1.Fang, JF (corresponding author), Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China. 2.Fang, JF (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. 3.Fang, JF (corresponding author), East China Normal Univ, Engn Res Ctr Nanophoton & Adv Instrument, Sch Phys & Elect Sci, Minist Educ, Shanghai 200241, Peoples R China.
推荐引用方式 GB/T 7714	Fu, Sheng,Li, Xiaodong,Wan, Li,et al. Effective Surface Treatment for High-Performance Inverted CsPbI2Br Perovskite Solar Cells with Efficiency of 15.92%[J]. NANO-MICRO LETTERS,2020,12(1).
APA	Fu, Sheng,Li, Xiaodong,Wan, Li,Zhang, Wenxiao,Song, Weijie,&Fang, Junfeng.(2020).Effective Surface Treatment for High-Performance Inverted CsPbI2Br Perovskite Solar Cells with Efficiency of 15.92%.NANO-MICRO LETTERS,12(1).
MLA	Fu, Sheng,et al."Effective Surface Treatment for High-Performance Inverted CsPbI2Br Perovskite Solar Cells with Efficiency of 15.92%".NANO-MICRO LETTERS 12.1(2020).