All-solid-state flexible zinc-air battery with polyacrylamide alkaline gel electrolyte

doi:10.1016/j.jpowsour.2019.227653

CORC > 宁波材料技术与工程研究所 > 中国科学院宁波材料技术与工程研究所 > 2020专题

	All-solid-state flexible zinc-air battery with polyacrylamide alkaline gel electrolyte
	Miao, He ; Chen, Bin ; Li, Shihua ; Wu, Xuyang ; Wang, Qin ; Zhang, Chunfei ; Sun, Zixu ; Li, Hong
刊名	JOURNAL OF POWER SOURCES
	2020
卷号	450
关键词	ELECTROCHEMICAL WATER OXIDATION NITROGEN-DOPED GRAPHENE OXYGEN REDUCTION POLYMER-ELECTROLYTE ELECTROCATALYTIC ACTIVITY BIFUNCTIONAL CATALYST HIGHLY EFFICIENT CARBON OXIDE NANOSTRUCTURES
DOI	10.1016/j.jpowsour.2019.227653
英文摘要	The rapid development of flexible electronic devices prompts the extensive attentions of the all-solid-state flexible zinc-air batteries (ZABs). Nevertheless, the low energy conversion efficiency and output power density hinder the practical application of all-solid-state flexible ZABs due to the lacks of bifunctional oxygen catalysts with high catalytic activity and flexible solid electrolytes with high ionic conductivity. Herein, we report an active and cost-effective oxygen catalyst of manganese dioxide (MnO2) nanowires supported on nitrogen-doped reduced graphene oxide (MnO2/NRGO.(Urea)) synthesized by a facile one-pot process. Along with superior stability, MnO2/NRGO-(Urea) shows the prominent activities for oxygen reduction and evolution reactions (ORR and OER), and lowest potential difference between ORR and OER among most of the manganese dioxides reported recently. Importantly, the polyacrylamide (PAM) based alkaline gel electrolyte (AGE) which shows much higher hydroxide-ion conductivity (215.6 mS cm(-2)) than the state-of-the-art polyvinyl alcohol (PVA)-based AGEs is employed in the all-solid-state flexible ZAB. Thanks to the MnO2/NRGO.(Urea) catalyst and PAM-based AGE, the maximum power density (P-max) of the as -fabricated all-solid-state flexible ZAB reaches 105.0 mW cm(-2) with extraordinary mechanical flexibility and robustness. Our work offers a cost-effective strategy for all-solid-state flexible ZABs with high power density and excellent energy conversion efficiency.
学科主题	Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
内容类型	期刊论文
源URL	[http://ir.nimte.ac.cn/handle/174433/19938]
专题	2020专题
作者单位	1.Li, H (corresponding author), Nanyang Technol Univ, Sch Mech & Aerosp Engn, Singapore 639798, Singapore. 2.Miao, H (corresponding author), Ningbo Univ, Fac Maritime & Transportat, Ningbo 315211, Peoples R China.
推荐引用方式 GB/T 7714	Miao, He,Chen, Bin,Li, Shihua,et al. All-solid-state flexible zinc-air battery with polyacrylamide alkaline gel electrolyte[J]. JOURNAL OF POWER SOURCES,2020,450.
APA	Miao, He.,Chen, Bin.,Li, Shihua.,Wu, Xuyang.,Wang, Qin.,...&Li, Hong.(2020).All-solid-state flexible zinc-air battery with polyacrylamide alkaline gel electrolyte.JOURNAL OF POWER SOURCES,450.
MLA	Miao, He,et al."All-solid-state flexible zinc-air battery with polyacrylamide alkaline gel electrolyte".JOURNAL OF POWER SOURCES 450(2020).