Synthesis and Application of Sustainable Furfuryl Alcohol-based Plasticizer
Chen, Hao; Ding, Jiheng; Liang, Hongzhe; Yu, Haibin
刊名CHEMISTRYSELECT
2020
卷号5期号:13页码:4085-4090
关键词BIO-BASED PLASTICIZER WASTE FRYING OIL THERMAL-DEGRADATION ETHOXYLATED ESTERS AEROBIC OXIDATION MALEIC-ANHYDRIDE PVC ACID MIGRATION
DOI10.1002/slct.202000697
英文摘要The application of green and sustainable plasticizers deriving from natural resources has become a promising way to replace conventional petroleum-based plasticizers like dioctyl phthalate (DOP). Herein, the environment-friendly plasticizer dioctyl 1-((octanoyloxy)methyl)-7-oxabicyclo-[2.2.1] hept-5-ene-2,3-dicarboxylate (DOMFC) was synthesized from a renewable resource, furfuryl alcohol and maleic anhydride, and its plasticization efficiencies in polyvinyl chloride (PVC) was studied. The tensile strain of PVC-DOMFC reached about 7.4 times higher than that of pure PVC, which was higher than that of PVC-DOP composites. Solvent extraction and thermal stability results indicated that the epoxy groups and ester bonds in DOMFC could efficiently increase the plasticizing effect, while the existence of furan rings improved the rigidity of the PVC. This design strategy opens an avenue for fabricating high-performance green plasticizers to replace DOP.
学科主题Chemistry
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/19807]  
专题2020专题
作者单位1.Liang, HZ (corresponding author), Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315201, Peoples R China.
2.Yu, HB (corresponding author), Chinese Acad Sci, Key Lab Marine Mat & Related Technol, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China.
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Chen, Hao,Ding, Jiheng,Liang, Hongzhe,et al. Synthesis and Application of Sustainable Furfuryl Alcohol-based Plasticizer[J]. CHEMISTRYSELECT,2020,5(13):4085-4090.
APA Chen, Hao,Ding, Jiheng,Liang, Hongzhe,&Yu, Haibin.(2020).Synthesis and Application of Sustainable Furfuryl Alcohol-based Plasticizer.CHEMISTRYSELECT,5(13),4085-4090.
MLA Chen, Hao,et al."Synthesis and Application of Sustainable Furfuryl Alcohol-based Plasticizer".CHEMISTRYSELECT 5.13(2020):4085-4090.
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