High performance 0.9LiMnPO(4)-0.1LiFePO(4)/C composite | |
Liu, Jian; Zhang, XianHui; Yang, WenChao; Liu, Meng; Ren, ZhongMin; Zhang, ShengQi; Wang, DeYu | |
刊名 | SCIENCE CHINA-TECHNOLOGICAL SCIENCES |
2020 | |
卷号 | 63期号:6页码:971-976 |
关键词 | CARBON-COATED LIFEPO4 CATHODE MATERIAL ELECTROCHEMICAL PERFORMANCE LIMNPO4 NANOCOMPOSITE |
DOI | 10.1007/s11431-019-1513-y |
英文摘要 | The rate performance of lithium manganese phosphate is seriously tarnished by its sluggish surface kinetics, which could be addressed by LiFePO4-surface coating. For a higher energy output, here we explore thinner coating layers with 10% and 5% LiFePO4 via the lab-developed DMSO assisted method. The core-shell structured 0.9LiMnPO(4)-0.1LiFePO(4)/C maintains a high specific capacity, 153, 148 and 140 mA h g(-1) under 0.1, 1 and 5 C respectively, which are the best results for this composition till date. As for 0.95LiMnPO(4)-0.05LiFePO(4)/C, the discharge capacity is lower than 110 mA h g(-1) even in 0.1 C, which cannot meet the requirements of practical application. Our approaches push the manganese ratio of LiMnPO4-based composite to 90% from 80%, further improving the energy-density of the olivine phosphates. |
学科主题 | Engineering ; Materials Science |
内容类型 | 期刊论文 |
源URL | [http://ir.nimte.ac.cn/handle/174433/19764] |
专题 | 2020专题 |
作者单位 | 1.Wang, DY (corresponding author), Tianmu Lake Inst Adv Energy Storage Technol, Liyang 213300, Peoples R China. 2.Zhang, XH 3.Wang, DY (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
推荐引用方式 GB/T 7714 | Liu, Jian,Zhang, XianHui,Yang, WenChao,et al. High performance 0.9LiMnPO(4)-0.1LiFePO(4)/C composite[J]. SCIENCE CHINA-TECHNOLOGICAL SCIENCES,2020,63(6):971-976. |
APA | Liu, Jian.,Zhang, XianHui.,Yang, WenChao.,Liu, Meng.,Ren, ZhongMin.,...&Wang, DeYu.(2020).High performance 0.9LiMnPO(4)-0.1LiFePO(4)/C composite.SCIENCE CHINA-TECHNOLOGICAL SCIENCES,63(6),971-976. |
MLA | Liu, Jian,et al."High performance 0.9LiMnPO(4)-0.1LiFePO(4)/C composite".SCIENCE CHINA-TECHNOLOGICAL SCIENCES 63.6(2020):971-976. |
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