Efficient and Selective Oxidation of 5-Hydroxymethylfurfural into 2, 5-Diformylfuran Catalyzed by Magnetic Vanadium-Based Catalysts with Air as Oxidant

doi:10.1007/s10562-019-03041-w

	Efficient and Selective Oxidation of 5-Hydroxymethylfurfural into 2, 5-Diformylfuran Catalyzed by Magnetic Vanadium-Based Catalysts with Air as Oxidant
	Lai, Jinhua 1; Zhou, Shuolin 1; Cheng, Feng 1; Guo, Dongwen 1; Liu, Xianxiang 1,2; Xu, Qiong 1; Yin, Dulin 1
刊名	CATALYSIS LETTERS
	2020-05-01
卷号	150 期号:5 页码:1301-1308
关键词	5-Hydroxymethylfurfural 2 5-Diformylfuran Selective oxidation Magnetic catalyst Biomass transformation
ISSN号	1011-372X
DOI	10.1007/s10562-019-03041-w
通讯作者	Liu, Xianxiang(lxx@hunnu.edu.cn) ; Yin, Dulin(dulinyin@126.com)
英文摘要	In this study, a new kind of magnetic vanadium-based catalyst was successfully prepared and employed to produce 2, 5-diformylfuran (DFF) in the liquid phase through selective oxidation of biomass-derived 5-hydroxymethylfurfur (HMF) with air as oxidant. It was found that magnetic Fe3O4 nanoparticles supported NH4 center dot V3O8 showed excellent catalytic performance with the achievement of 95.5% HMF conversion along with 82.9% selectivity to DFF under optimal reaction conditions. More importantly, the catalyst could be readily separated from the reaction mixture by a permanent magnet, and recycled several times without the loss of its catalytic activity. Graphic The NH4 center dot V3O8/Fe3O4 catalyst showed high activity for selective oxidation of 5-hydroxymethylfurfural into 2, 5-diformylfuran.
WOS关键词	AEROBIC OXIDATION ; VPO CATALYSTS ; H-BETA ; 2,5-DIFORMYLFURAN ; DERIVATIVES ; CONVERSION ; CARBON
WOS研究方向	Chemistry
语种	英语
出版者	SPRINGER
WOS记录号	WOS:000523031800009
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/26721]
专题	中国科学院广州能源研究所
通讯作者	Liu, Xianxiang; Yin, Dulin
作者单位	1.Hunan Normal Univ, Natl & Local Joint Engn Lab New Petrochem Mat & F, Key Lab Assembly & Applicat Organ Funct Mol Hunan, Changsha 410081, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
推荐引用方式 GB/T 7714	Lai, Jinhua,Zhou, Shuolin,Cheng, Feng,et al. Efficient and Selective Oxidation of 5-Hydroxymethylfurfural into 2, 5-Diformylfuran Catalyzed by Magnetic Vanadium-Based Catalysts with Air as Oxidant[J]. CATALYSIS LETTERS,2020,150(5):1301-1308.
APA	Lai, Jinhua.,Zhou, Shuolin.,Cheng, Feng.,Guo, Dongwen.,Liu, Xianxiang.,...&Yin, Dulin.(2020).Efficient and Selective Oxidation of 5-Hydroxymethylfurfural into 2, 5-Diformylfuran Catalyzed by Magnetic Vanadium-Based Catalysts with Air as Oxidant.CATALYSIS LETTERS,150(5),1301-1308.
MLA	Lai, Jinhua,et al."Efficient and Selective Oxidation of 5-Hydroxymethylfurfural into 2, 5-Diformylfuran Catalyzed by Magnetic Vanadium-Based Catalysts with Air as Oxidant".CATALYSIS LETTERS 150.5(2020):1301-1308.