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Hydrodeoxygenation of lignocellulose-derived oxygenates to diesel or jet fuel range alkanes under mild conditions
Li, Kui1; Zhou, Feng2; Liu, Xiaohao3; Ma, Huixia2; Deng, Jin1; Xu, Guangyue1; Zhang, Ying1,4
刊名CATALYSIS SCIENCE & TECHNOLOGY
2020-02-21
卷号10期号:4页码:1151-1160
ISSN号2044-4753
DOI10.1039/c9cy02367d
通讯作者Zhang, Ying(zhzhying@ustc.edu.cn)
英文摘要Hydrodeoxygenation (HDO) of lignocellulose-derived oxygenates to diesel or jet fuel range C8-C18 alkanes usually requires harsh reaction conditions. A fairly mild (160 degrees C, 4 MPa H-2) one-pot catalytic HDO system based on Ru/HAP combined with the HZSM-5 catalyst was developed, and a series of diesel or jet fuel range alkanes (C8-C18), including straight, branched, and cyclic alkanes, were obtained from nine complicated lignocellulose-derived oxygenates with a desired yield. Ru/HAP was characterized by a series of analyses, indicating that the electron donor effect of HAP led to the generation of highly dispersed electron-rich Ru, which demonstrated stronger hydrogen activation and hydrogenolysis ability.
资助项目National Key R&D Program of China[2018YFB1501502] ; NSFC[51876200] ; DNL Cooperation Fund, CAS[DNL180301]
WOS关键词HIGH-QUALITY DIESEL ; CATALYTIC CONVERSION ; SELECTIVE HYDROGENATION ; GAMMA-VALEROLACTONE ; PHASE DEHYDRATION ; RENEWABLE DIESEL ; LEVULINIC ACID ; HAP CATALYST ; JATROPHA OIL ; HYDROXYAPATITE
WOS研究方向Chemistry
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000518579100021
资助机构National Key R&D Program of China ; NSFC ; DNL Cooperation Fund, CAS
内容类型期刊论文
源URL[http://ir.giec.ac.cn/handle/344007/26568]  
专题中国科学院广州能源研究所
通讯作者Zhang, Ying
作者单位1.Univ Sci & Technol China, Dept Appl Chem, CAS Key Lab Urban Pollutant Convers, Hefei 230026, Peoples R China
2.SINOPEC, Fushun Res Inst Petr & Petrochem, Fushun 113001, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
4.Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116011, Peoples R China
推荐引用方式
GB/T 7714
Li, Kui,Zhou, Feng,Liu, Xiaohao,et al. Hydrodeoxygenation of lignocellulose-derived oxygenates to diesel or jet fuel range alkanes under mild conditions[J]. CATALYSIS SCIENCE & TECHNOLOGY,2020,10(4):1151-1160.
APA Li, Kui.,Zhou, Feng.,Liu, Xiaohao.,Ma, Huixia.,Deng, Jin.,...&Zhang, Ying.(2020).Hydrodeoxygenation of lignocellulose-derived oxygenates to diesel or jet fuel range alkanes under mild conditions.CATALYSIS SCIENCE & TECHNOLOGY,10(4),1151-1160.
MLA Li, Kui,et al."Hydrodeoxygenation of lignocellulose-derived oxygenates to diesel or jet fuel range alkanes under mild conditions".CATALYSIS SCIENCE & TECHNOLOGY 10.4(2020):1151-1160.
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