Continuous Production of 5-Hydroxymethylfurfural from Monosaccharide over Zirconium Phosphates

doi:10.1002/slct.201801880

	Continuous Production of 5-Hydroxymethylfurfural from Monosaccharide over Zirconium Phosphates
	Zhu, Changhui 1,2,3,4; Cai, Chiliu 1,2,3; Liu, Qiying 1,2,3; Li, Wenzhi 5; Tan, Jin 1,2,3; Wang, Chenguang 1,2,3; Chen, Lungang 1,2,3; Zhang, Qi 1,2,3; Ma, Longlong 1,2,3
刊名	CHEMISTRYSELECT
	2018-10-24
卷号	3 期号:39 页码:10983-10990
关键词	dehydration fixed bed 5-hydroxymethylfurfural monosaccharide zirconium phosphate
ISSN号	2365-6549
DOI	10.1002/slct.201801880
通讯作者	Liu, Qiying(liuciy@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
英文摘要	5-hydroxymethylfurfural (HMF), an important platform compound produced from lignocellulosic biomass, is widely applied in petrochemical industry for downstream synthesis of medical supplies or intermediate of the other important chemicals by the typical catalytic processes. A continuous production route was developed to yield HMF from monosaccharides by using zirconium phosphate (ZrP) with different Zr/P ratios as catalysts. Its physicochemical properties were then characterized by Brunauer-Emmett-Teller (BET), X-ray powder diffraction (XRD), X-ray photoelectron spectra (XPS), Fourier transform infrared spectroscopy (FT-IR), pyridine adsorbed Fourier transform infrared spectroscopy (Py-FT-IR), X-ray fluorescence (XRF) and temperature programmed desorption of ammonia (NH3-TPD) techniques. A mixed phase containing monosaccharide in aqueous and dimethyl sulfoxide (DMSO) phase was applied in the fixed bed to keep the continuous production. The optimized reaction conditions were applied to maximized HMF yield by varying the processing parameters. The highest HMF yield of 56.3% was obtained when using fructose as the feedstock under the reaction condition of 120 degrees C, 180min, N-2 pressure 2MPa and DMSO: fructose solution of 9:1 over ZrP with the P/Zr with molar ratio of 2. Comparatively, the glucose conversion of 72% with the HMF yield of 32% were gained under the same conditions using glucose as the feedstock. It is deduced that the ZrP catalysts simultaneously possessing Bronsted/Lewis acid showed synergy in glucose dehydration to HMF. The ZrP catalyst showed good stability and no obvious deactivation was observed after 30h of time-on-stream, due to the primary structure and acidic properties of catalyst can be kept during the reaction. Finally, it is generally efficient for some C-6 sugars dehydration to HMF with the Bronsted/Lewis acid synergy of ZrP.
资助项目	National Science Foundation of China[51536009] ; National Science Foundation of China[51576199] ; Natural Science Foundation of Guangdong Province[2017 A030308010] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01 N092]
WOS关键词	IONIC LIQUID ; SOLID ACID ; D-FRUCTOSE ; HETEROGENEOUS ZIRCONIUM ; CONVERSION ; DEHYDRATION ; BIOMASS ; CATALYSTS ; GLUCOSE ; HMF
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000449032600023
资助机构	National Science Foundation of China ; Natural Science Foundation of Guangdong Province ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/24158]
专题	中国科学院广州能源研究所
通讯作者	Liu, Qiying; Ma, Longlong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Changhui,Cai, Chiliu,Liu, Qiying,et al. Continuous Production of 5-Hydroxymethylfurfural from Monosaccharide over Zirconium Phosphates[J]. CHEMISTRYSELECT,2018,3(39):10983-10990.
APA	Zhu, Changhui.,Cai, Chiliu.,Liu, Qiying.,Li, Wenzhi.,Tan, Jin.,...&Ma, Longlong.(2018).Continuous Production of 5-Hydroxymethylfurfural from Monosaccharide over Zirconium Phosphates.CHEMISTRYSELECT,3(39),10983-10990.
MLA	Zhu, Changhui,et al."Continuous Production of 5-Hydroxymethylfurfural from Monosaccharide over Zirconium Phosphates".CHEMISTRYSELECT 3.39(2018):10983-10990.