Atmospheric nitrous acid (HONO) at a rural coastal site in North China: Seasonal variations and effects of biomass burning

doi:10.1016/j.atmosenv.2020.117429

CORC > 烟台海岸带研究所 > 中国科学院烟台海岸带研究所 > 中科院海岸带环境过程与生态修复重点实验室 > 近岸生态与环境实验室

	Atmospheric nitrous acid (HONO) at a rural coastal site in North China: Seasonal variations and effects of biomass burning
	Gu, Rongrong ; Zheng, Penggang ; Chen, Tianshu ; Dong, Can ; Wang, Ya'nan ; Liu, Yiming ; Liu, Yuhong ; Luo, Yuanyuan ; Han, Guangxuan ; Wang, Xinfeng
刊名	ATMOSPHERIC ENVIRONMENT
	2020-05-15
卷号	229 页码:117429
关键词	YELLOW-RIVER DELTA NITRIC-OXIDE URBAN ATMOSPHERE CHEMISTRY EMISSIONS NO2 PHOTOLYSIS SURFACES DIOXIDE NITRATE
DOI	10.1016/j.atmosenv.2020.117429
产权排序	[Gu, Rongrong ; Zheng, Penggang ; Chen, Tianshu ; Dong, Can ; Liu, Yuhong ; Luo, Yuanyuan ; Wang, Xinfeng ; Zhou, Xuehua ; Wang, Wenxing ; Xue, Likun] Shandong Univ, Environm Res Inst, Qingdao 266237, Peoples R China ; [Gu, Rongrong ; Wang, Ya'nan ; Liu, Yiming ; Wang, Tao] Hong Kong Polytech Univ, Dept Civil & Environm Engn, Hong Kong 99907, Peoples R China ; [Han, Guangxuan] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Yantai 264003, Peoples R China ; [Xue, Likun] Jinan Inst Environm Sci, Jinan 250100, Peoples R China
文献子类	Article
英文摘要	Nitrous acid (HONO) plays a significant role in atmospheric chemistry due to its contribution to hydroxyl radical (OH). However, no scientific consensus has been achieved about the daytime HONO formation mechanisms. To identify the seasonal variations of HONO chemistry and the impacts of biomass burning (BB), we performed a two-phased field study in winter-spring and summer (covering a harvest season) in 2017 at a rural coastal site in North China. Though the mean HONO concentration in winter-spring (0.26 +/- 0.28 ppbv) was higher than in summer (0.17 + 0.19 ppbv), the maximum HONO concentrations were comparable (similar to 2 ppbv) in the two campaigns. Both the HONO/NOx ratio and nocturnal heterogeneous conversion efficiency of HONO (C-HONO) in summer were over twice of that in winter-spring. The daytime budget analysis also revealed that the strength of P(othe)r (i.e., the HONO sources apart from the reaction of OH + NO) in summer was double of that in winter-spring. BB affected the HONO concentration by enhancing the contribution of heterogeneous HONO production on the aerosol surface but weakening the role of photo-related HONO formation. HONO photolysis was a significant source of OH in both winter-spring and summer, and its contribution could be further enhanced during the BB episode in summer. Our study demonstrates the significant seasonal variations of HONO and the effects of BB, and suggests needs for more multi-season observations and considerations of BB, especially during the harvest time, in HONO research.
WOS关键词	YELLOW-RIVER DELTA ; NITRIC-OXIDE ; URBAN ATMOSPHERE ; CHEMISTRY ; EMISSIONS ; NO2 ; PHOTOLYSIS ; SURFACES ; DIOXIDE ; NITRATE
语种	英语
WOS记录号	WOS:000530031600004
资助机构	National Natural Science Foundation of ChinaNational Natural Science Foundation of China [41675118, 91544213, 41505111] ; Hong Kong Research Grants CouncilHong Kong Research Grants Council [T24-504/17-N] ; Shandong Provincial Natural Science Foundation for Distinguished Young Scholars [ZR2019JQ09] ; Qilu Youth Talent Program of Shandong University ; Jiangsu Collaborative Innovation Center for Climate Change
内容类型	期刊论文
源URL	[http://ir.yic.ac.cn/handle/133337/25032]
专题	烟台海岸带研究所_近岸生态与环境实验室烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
作者单位	1.Hong Kong Polytech Univ, Dept Civil & Environm Engn, Hong Kong 99907, Peoples R China; 2.Jinan Inst Environm Sci, Jinan 250100, Peoples R China 3.Shandong Univ, Environm Res Inst, Qingdao 266237, Peoples R China; 4.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Zone Environm Proc & Ecol Remedia, Yantai 264003, Peoples R China;
推荐引用方式 GB/T 7714	Gu, Rongrong,Zheng, Penggang,Chen, Tianshu,et al. Atmospheric nitrous acid (HONO) at a rural coastal site in North China: Seasonal variations and effects of biomass burning[J]. ATMOSPHERIC ENVIRONMENT,2020,229:117429.
APA	Gu, Rongrong.,Zheng, Penggang.,Chen, Tianshu.,Dong, Can.,Wang, Ya'nan.,...&Xue, Likun.(2020).Atmospheric nitrous acid (HONO) at a rural coastal site in North China: Seasonal variations and effects of biomass burning.ATMOSPHERIC ENVIRONMENT,229,117429.
MLA	Gu, Rongrong,et al."Atmospheric nitrous acid (HONO) at a rural coastal site in North China: Seasonal variations and effects of biomass burning".ATMOSPHERIC ENVIRONMENT 229(2020):117429.