Catalytic ozonation of nitroimidazole antibiotics using nano-magnesium hydroxide as heavy-metals free catalyst

doi:10.5004/dwt.2019.24277

CORC > 烟台海岸带研究所 > 中国科学院烟台海岸带研究所 > 中科院海岸带环境过程与生态修复重点实验室 > 近岸生态与环境实验室

	Catalytic ozonation of nitroimidazole antibiotics using nano-magnesium hydroxide as heavy-metals free catalyst
	Sun, Q ; Zhu, GC ; Wu, J ; Lu, J ; Zhang, ZH
刊名	DESALINATION AND WATER TREATMENT
	2019-09
卷号	161 页码:216-227
关键词	Nano-scale magnesium hydroxide Nitroimidazole antibiotics Catalytic ozonation Degradation
ISSN号	1944-3994
DOI	10.5004/dwt.2019.24277
产权排序	[Sun, Qi ; Zhu, Guangcan] Southeast Univ, Sch Energy & Environm, Nanjing 210096, Jiangsu, Peoples R China ; [Wu, Jun ; Zhang, Zhenhua] Ludong Univ, Sch Resources & Environm Engn, Yantai 264025, Shandong, Peoples R China ; [Lu, Jian] Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China ; [Lu, Jian] YICCAS, Shandong Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China
文献子类	Article
英文摘要	In this study, nano-magnesium hydroxide (nano-Mg(OH)(2)) was prepared and first applied for the catalytic ozonation of the widely used nitroimidazole antibiotics. Most of nitroimidazole antibiotics were rapidly removed within 10 min. The removal rate constant of metronidazole in the catalytic ozonation treatment was four times higher than that without catalyst. Persistent high catalytic activity of nano-Mg(OH)(2) maintained after three runs. The severe inhibition of hydroxyl radical scavenger (TBA) on the catalytic ozonation suggested that hydroxyl radical reaction served as the predominant process. The removal of nitroimidazole antibiotics followed a pseudo-first order kinetic model. Increase in the dosage of catalyst and reaction temperature within certain range could enhance the degradation of metronidazole, tinidazole, and dimetridazole while increase in the initial concentration of nitroimidazole antibiotics led to the decrease in the removal efficiency. All anions (Cl-, HCO3, and SO42-) and cations (Ca2+ and Mg2+) had negative influence on the removal efficiency of nitroimidazole antibiotics. Due to the unique features such as low cost and heavy-metals free, high efficiency and persistent high catalytic activity of the nano-Mg(OH)(2) in the catalytic ozonation of nitroimidazole antibiotics demonstrated that nano-Mg(OH)(2) is a promising environment-friendly ozonation catalyst in terms of antibiotic removal.
WOS关键词	WASTE-WATER ; 2,4-DICHLOROPHENOXYACETIC ACID ; PHOTOCATALYTIC DEGRADATION ; AQUATIC ENVIRONMENT ; INORGANIC-COMPOUNDS ; AQUEOUS-SOLUTION ; RATE CONSTANTS ; REMOVAL ; OZONE ; SULFAMETHOXAZOLE
WOS研究方向	Engineering, Chemical ; Water Resources
语种	英语
WOS记录号	WOS:000472928900021
资助机构	National Natural Science Foundation of ChinaNational Natural Science Foundation of China [41877131, 51578132] ; One Hundred Talents Program of Chinese Academy of SciencesChinese Academy of Sciences [Y629041021] ; Taishan Scholar Program of Shandong Province [tsqn201812116] ; Two-Hundred Talents Plan of Yantai [Y739011021]
内容类型	期刊论文
源URL	[http://ir.yic.ac.cn/handle/133337/24877]
专题	烟台海岸带研究所_近岸生态与环境实验室烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
作者单位	1.Chinese Acad Sci, Yantai Inst Coastal Zone Res YIC, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Shandong, Peoples R China; 2.Southeast Univ, Sch Energy & Environm, Nanjing 210096, Jiangsu, Peoples R China; 3.YICCAS, Shandong Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China 4.Ludong Univ, Sch Resources & Environm Engn, Yantai 264025, Shandong, Peoples R China;
推荐引用方式 GB/T 7714	Sun, Q,Zhu, GC,Wu, J,et al. Catalytic ozonation of nitroimidazole antibiotics using nano-magnesium hydroxide as heavy-metals free catalyst[J]. DESALINATION AND WATER TREATMENT,2019,161:216-227.
APA	Sun, Q,Zhu, GC,Wu, J,Lu, J,&Zhang, ZH.(2019).Catalytic ozonation of nitroimidazole antibiotics using nano-magnesium hydroxide as heavy-metals free catalyst.DESALINATION AND WATER TREATMENT,161,216-227.
MLA	Sun, Q,et al."Catalytic ozonation of nitroimidazole antibiotics using nano-magnesium hydroxide as heavy-metals free catalyst".DESALINATION AND WATER TREATMENT 161(2019):216-227.