Long-Range Ordered Amorphous Atomic Chains as Building Blocks of a Superconducting Quasi-One-Dimensional Crystal
An, Chao5; Zhou, Yonghui1; Chen, Chunhua1; Fei, Fucong6; Song, Fengqi6; Park, Changyong7; Zhou, Jianhui1; Rubahn, Horst-Gunter3,4; Moshchalkov, Victor V.2; Chen, Xuliang1
刊名ADVANCED MATERIALS
2020-07-23
关键词combination of crystalline and amorphous structures high pressures linear chain compound quasi-1D materials superconductivity
ISSN号0935-9648
DOI10.1002/adma.202002352
通讯作者Chen, Xuliang(xlchen@hmfl.ac.cn) ; Zhang, Gufei(gufei@mci.sdu.dk) ; Yang, Zhaorong(zryang@issp.ac.cn)
英文摘要

Crystalline and amorphous structures are two of the most common solid-state phases. Crystals having orientational and periodic translation symmetries are usually both short-range and long-range ordered, while amorphous materials have no long-range order. Short-range ordered but long-range disordered materials are generally categorized into amorphous phases. In contrast to the extensively studied crystalline and amorphous phases, the combination of short-range disordered and long-range ordered structures at the atomic level is extremely rare and so far has only been reported for solvated fullerenes under compression. Here, a report on the creation and investigation of a superconducting quasi-1D material with long-range ordered amorphous building blocks is presented. Using a diamond anvil cell, monocrystalline (TaSe4)(2)I is compressed and a system is created where the TaSe(4)atomic chains are in amorphous state without breaking the orientational and periodic translation symmetries of the chain lattice. Strikingly, along with the amorphization of the atomic chains, the insulating (TaSe4)(2)I becomes a superconductor. The data provide critical insight into a new phase of solid-state materials. The findings demonstrate a first ever case where superconductivity is hosted by a lattice with periodic but amorphous constituent atomic chains.

资助项目National Key Research and Development Program of China[2018YFA0305704] ; National Key Research and Development Program of China[2016YFA0401804] ; National Natural Science Foundation of China[11574323] ; National Natural Science Foundation of China[U1632275] ; National Natural Science Foundation of China[U19A2093] ; National Natural Science Foundation of China[U1932152] ; National Natural Science Foundation of China[11874362] ; National Natural Science Foundation of China[11704387] ; National Natural Science Foundation of China[11804344] ; National Natural Science Foundation of China[11804341] ; National Natural Science Foundation of China[U1832209] ; National Natural Science Foundation of China[U1732273] ; National Natural Science Foundation of China[11904165] ; National Natural Science Foundation of China[11904166] ; National Natural Science Foundation of China[11605276] ; Natural Science Foundation of Anhui Province[1808085MA06] ; Natural Science Foundation of Anhui Province[1908085QA18] ; Users with Excellence Project of Hefei Center CAS[2018HSC-UE012] ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology[2018ZYFX002] ; Youth Innovation Promotion Association CAS[2020443] ; High Magnetic Field Laboratory of Anhui Province ; DOE-NNSA's Office of Experimental Sciences ; DOE Office of Science[DE-AC02-06CH11357]
WOS关键词CHARGE-DENSITY-WAVE ; TRANSITION ; (TASE4)2I ; CONDUCTIVITY ; TEMPERATURE ; DEPENDENCE
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000551445600001
资助机构National Key Research and Development Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Anhui Province ; Users with Excellence Project of Hefei Center CAS ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Youth Innovation Promotion Association CAS ; High Magnetic Field Laboratory of Anhui Province ; DOE-NNSA's Office of Experimental Sciences ; DOE Office of Science
内容类型期刊论文
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/43227]  
专题合肥物质科学研究院_中科院强磁场科学中心
通讯作者Chen, Xuliang; Zhang, Gufei; Yang, Zhaorong
作者单位1.Chinese Acad Sci, Anhui Prov Key Lab Condensed Matter Phys Extreme, High Magnet Field Lab, Hefei 230031, Peoples R China
2.Katholieke Univ Leuven, Celestijnenlaan 200D, B-3001 Leuven, Belgium
3.Univ Southern Denmark, DIAS Danish Inst Adv Study, Alsion 2, DK-6400 Sonderborg, Denmark
4.Univ Southern Denmark, Mads Clausen Inst, NanoSYD, Alsion 2, DK-6400 Sonderborg, Denmark
5.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Peoples R China
6.Nanjing Univ, Sch Phys, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
7.Argonne Natl Lab, Xray Sci Div, HPCAT, 9700 S Cass Ave, Argonne, IL 60439 USA
推荐引用方式
GB/T 7714
An, Chao,Zhou, Yonghui,Chen, Chunhua,et al. Long-Range Ordered Amorphous Atomic Chains as Building Blocks of a Superconducting Quasi-One-Dimensional Crystal[J]. ADVANCED MATERIALS,2020.
APA An, Chao.,Zhou, Yonghui.,Chen, Chunhua.,Fei, Fucong.,Song, Fengqi.,...&Yang, Zhaorong.(2020).Long-Range Ordered Amorphous Atomic Chains as Building Blocks of a Superconducting Quasi-One-Dimensional Crystal.ADVANCED MATERIALS.
MLA An, Chao,et al."Long-Range Ordered Amorphous Atomic Chains as Building Blocks of a Superconducting Quasi-One-Dimensional Crystal".ADVANCED MATERIALS (2020).
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