Large Single-Crystal Cu Foils with High-Index Facets by Strain-Engineered Anomalous Grain Growth

doi:10.1002/adma.202002034

CORC > 力学研究所 > 中国科学院力学研究所 > 非线性力学国家重点实验室

	Large Single-Crystal Cu Foils with High-Index Facets by Strain-Engineered Anomalous Grain Growth
	Li YLZ 2,3,4; Sun LZ 2,3,4; Chang ZH(常正华)5,6; Liu HY 2,4; Wang YC 2,3,4; Liang Y 2; Chen BH 2; Ding QJ 2; Zhao ZY 2; Wang RY 2,4
刊名	ADVANCED MATERIALS
	2020-06-11
页码	7
关键词	anomalous grain growth Cu foils high-index facets single-crystals strain-engineering
ISSN号	0935-9648
DOI	10.1002/adma.202002034
英文摘要	The rich and complex arrangements of metal atoms in high-index metal facets afford appealing physical and chemical properties, which attracts extensive research interest in material science for the applications in catalysis and surface chemistry. However, it is still a challenge to prepare large-area high-index single crystals in a controllable and cost-efficient manner. Herein, entire commercially available decimeter-sized polycrystalline Cu foils are successfully transformed into single crystals with a series of high-index facets, relying on a strain-engineered anomalous grain growth technique. The introduction of a moderate thermal-contact stress upon the Cu foil during the annealing leads to the formation of high-index grains dominated by the thermal strain of the Cu foils, rather than the (111) surface driven by the surface energy. Besides, the designed static gradient of the temperature enables the as-formed high-index grain seed to expand throughout the entire Cu foil. The as-received high-index Cu foils can serve as the templates for producing high-index single-crystal Cu-based alloys. This work provides an appealing material basis for the epitaxial growth of 2D materials, and the applications that require the unique surface structures of high-index metal foils and their alloys.
分类号	一类
WOS关键词	COPPER ; GRAPHENE ; CO2 ; SURFACES ; LAYER
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种	英语
WOS记录号	WOS:000539595800001
资助机构	Beijing National Laboratory for Molecular Science ; Beijing Municipal Science & Technology Commission[Z181100004818001] ; National Basic Research Program of China[2016YFA0200101] ; National Natural Science Foundation of China[21525310] ; National Natural Science Foundation of China[51432002] ; National Natural Science Foundation of China[51520105003] ; National Natural Science Foundation of China[11988102]
其他责任者	Wei, Yujie ; Peng, Hailin ; Lin, Li ; Liu, Zhongfan
内容类型	期刊论文
源URL	[http://dspace.imech.ac.cn/handle/311007/84765]
专题	力学研究所_非线性力学国家重点实验室
作者单位	1.Univ Manchester, Sch Phys & Astron, Manchester M13 9PL, Lancs, England 2.Beijing Graphene Inst, Beijing 100095, Peoples R China; 3.Peking Univ, Acad Adv Interdisciplinary Studies, Beijing 100871, Peoples R China; 4.Peking Univ, Coll Chem & Mol Engn, Ctr Nanochem, Beijing Sci & Engn Ctr Nanocarbons,Beijing Natl L, Beijing 100871, Peoples R China; 5.Chinese Acad Sci, Inst Mech, LNM, Beijing 100190, Peoples R China; 6.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China;
推荐引用方式 GB/T 7714	Li YLZ,Sun LZ,Chang ZH,et al. Large Single-Crystal Cu Foils with High-Index Facets by Strain-Engineered Anomalous Grain Growth[J]. ADVANCED MATERIALS,2020:7.
APA	Li YLZ.,Sun LZ.,常正华.,Liu HY.,Wang YC.,...&Liu ZF.(2020).Large Single-Crystal Cu Foils with High-Index Facets by Strain-Engineered Anomalous Grain Growth.ADVANCED MATERIALS,7.
MLA	Li YLZ,et al."Large Single-Crystal Cu Foils with High-Index Facets by Strain-Engineered Anomalous Grain Growth".ADVANCED MATERIALS (2020):7.