Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)center dot 2H(2)O | |
Wang Yongjiang; Pan Shilie; Tian Xuelin; Zhou Zhongxiang; Liu Gang; Wang Jide; Jia Dianzeng | |
刊名 | INORGANIC CHEMISTRY |
2009 | |
卷号 | 48期号:16页码:7800-7804 |
ISSN号 | 0020-1669 |
DOI | 10.1021/ic900700u |
英文摘要 | Single crystal of hydrated sodium borate Na2B5O8(OH)center dot 2H(2)O has been grown with sizes up to 5 x 5 x 3 mm(3) under mild hydrothermal conditions at 180 degrees C. The structure is determined by single-crystal X-ray diffraction and further characterized by IR and TG analyses. It crystallizes in the orthorhombic space group Pna2(1), with a = 11.967(2) angstrom, b = 6.5320(13) angstrom, c = 11.126(2) angstrom, Z = 4, R1 = 0.0183, and wR2 = 0.0483. The crystal structure of Na2B5O8(OH)center dot 2H(2)O is made up of Na-O polyhedra, and B5O8(OH)(2-) polyborate anions. Transmittance spectrum is performed on the Na2B5O8(OH)center dot 2H(2)O crystal, which shows an absorption edge less than 190 nm in the UV region. The powder second-harmonic generation intensity measured by the Kurtz-Perry method indicates that Na2B5O8 center dot(OH)center dot 2H(2)O is about half that of KH2PO4 (KDP). |
学科主题 | Chemistry |
WOS记录号 | WOS:000268661500039 |
公开日期 | 2012-11-29 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/1880] |
专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 |
通讯作者 | Pan Shilie |
作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China |
推荐引用方式 GB/T 7714 | Wang Yongjiang,Pan Shilie,Tian Xuelin,et al. Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)center dot 2H(2)O[J]. INORGANIC CHEMISTRY,2009,48(16):7800-7804. |
APA | Wang Yongjiang.,Pan Shilie.,Tian Xuelin.,Zhou Zhongxiang.,Liu Gang.,...&Jia Dianzeng.(2009).Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)center dot 2H(2)O.INORGANIC CHEMISTRY,48(16),7800-7804. |
MLA | Wang Yongjiang,et al."Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)center dot 2H(2)O".INORGANIC CHEMISTRY 48.16(2009):7800-7804. |
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