Rh(III)- or Ir(III)-catalyzed ynone synthesis from aldehydes via chelation-assisted C-H bond activation

doi:10.1039/c5cc00758e

	Rh(III)- or Ir(III)-catalyzed ynone synthesis from aldehydes via chelation-assisted C-H bond activation
	Ai, Wen 1,2; Wu, Yunxiang 2; Tang, Huanyu 2; Yang, Xueyan 1; Yang, Yaxi2 ; Li, Yuanchao 2; Zhou, Bing2
刊名	CHEMICAL COMMUNICATIONS
	2015
卷号	51 期号:37 页码:7871-7874
ISSN号	1359-7345
DOI	10.1039/c5cc00758e
文献子类	Article
英文摘要	A Rh(III)- or Ir(III)-catalyzed direct aldehyde C-H alkynylation was developed for the first time as a simple and practical method for the synthesis of ynones. This catalytic reaction proceeds under mild reaction conditions and tolerates a variety of synthetically important functional groups (e.g., chloro, bromo, aldehyde), thus providing a good complement to previous methods.
资助项目	National Natural Science Foundation of China[21302200]
WOS关键词	3-COMPONENT PYRIMIDINE SYNTHESIS ; N-SULFONYL 2-AMINOBENZALDEHYDES ; CATALYZED DIRECT ALKYNYLATION ; ROOM-TEMPERATURE ; EFFICIENT SYNTHESIS ; 2,5-DISUBSTITUTED FURANS ; ACETYLENIC KETONES ; TERMINAL ALKYNES ; RHODIUM COMPLEX ; ACID-CHLORIDES
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000353639300023
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/276734]
专题	药物化学研究室
通讯作者	Yang, Yaxi
作者单位	1.E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China; 2.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China
推荐引用方式 GB/T 7714	Ai, Wen,Wu, Yunxiang,Tang, Huanyu,et al. Rh(III)- or Ir(III)-catalyzed ynone synthesis from aldehydes via chelation-assisted C-H bond activation[J]. CHEMICAL COMMUNICATIONS,2015,51(37):7871-7874.
APA	Ai, Wen.,Wu, Yunxiang.,Tang, Huanyu.,Yang, Xueyan.,Yang, Yaxi.,...&Zhou, Bing.(2015).Rh(III)- or Ir(III)-catalyzed ynone synthesis from aldehydes via chelation-assisted C-H bond activation.CHEMICAL COMMUNICATIONS,51(37),7871-7874.
MLA	Ai, Wen,et al."Rh(III)- or Ir(III)-catalyzed ynone synthesis from aldehydes via chelation-assisted C-H bond activation".CHEMICAL COMMUNICATIONS 51.37(2015):7871-7874.