Research Progress in Metal-Catalyzed Addition of Carbon-Hetero Bonds to Alkynes

doi:10.6023/cjoc201607035

	Research Progress in Metal-Catalyzed Addition of Carbon-Hetero Bonds to Alkynes
	Zhao Fei 1; Jia Xiuwen 1; Wang Dongping 1; Fei Chaoli 1; Wu Chenglin 2,3; Wang Jiang2,3 ; Liu Hong2,3
刊名	CHINESE JOURNAL OF ORGANIC CHEMISTRY
	2017-02-25
卷号	37 期号:2 页码:284-300
关键词	metal-catalyzed carbon-hetero bonds alkynes addition reactions
ISSN号	0253-2786
DOI	10.6023/cjoc201607035
文献子类	Review
英文摘要	The addition of carbon-hetero bonds to alkynes has become an important apporach for the functionalization of carbon-carbon triple bonds. It can construct two bonds, namely one carbon-carbon bond and one carbon-hetero bond, in a single one step. These addition reactions feature high efficiency and high atom-economy. In recent years, metal-catalyzed (Al, Fe, Ni, Cu, Ga, Ru, Rh, Pd, Hf, Ir, Pt, Au, Bi, etc.) addition of many various kinds of carbon-hetero bonds to alkynes has achieved lots of important developments. According to the types of carbon-hetero bonds, the addition of 8 different kinds of carbon-hetero bonds [C-H, C-B, C-N, C-O, C-Si, C-S, C-X (X=Cl, Br, I), C-Se] to alkynes is reviewed in this paper, and the reaction conditions, reaction selectivities (regioselectivities and stereoselectivities) and reaction mechanisms are also discussed and summarized.
资助项目	National Natural Science Foundation of China[21602022] ; National Natural Science Foundation of China[21372235] ; Open Project Program of Antibiotics Research and Re-evaluation Key Laboratory of Sichuan Province[ARRLKF15-01]
WOS关键词	C-N BOND ; INTRAMOLECULAR TRANS-VINYLSILYLATION ; TERMINAL ALKYNES ; UNACTIVATED ALKYNES ; ACID-CHLORIDES ; REGIOSELECTIVE CYANOTHIOLATION ; 2,3-DISUBSTITUTED BENZOFURANS ; CYCLOISOMERIZATION REACTION ; STEREOSELECTIVE-SYNTHESIS ; CONVENIENT SYNTHESIS
WOS研究方向	Chemistry
语种	中文
CSCD记录号	CSCD:5947933
出版者	SCIENCE PRESS
WOS记录号	WOS:000397808100003
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/272766]
专题	药物化学研究室
通讯作者	Liu Hong
作者单位	1.Chengdu Univ, Sichuan Ind Inst Antibiot, Antibiot Res & Reevaluat Key Lab Sichuan Prov, Chengdu 610052, Peoples R China; 2.Chinese Acad Sci, Shanghai Inst Mat Med, Key Lab Receptor Res, Shanghai 201203, Peoples R China; 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhao Fei,Jia Xiuwen,Wang Dongping,et al. Research Progress in Metal-Catalyzed Addition of Carbon-Hetero Bonds to Alkynes[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2017,37(2):284-300.
APA	Zhao Fei.,Jia Xiuwen.,Wang Dongping.,Fei Chaoli.,Wu Chenglin.,...&Liu Hong.(2017).Research Progress in Metal-Catalyzed Addition of Carbon-Hetero Bonds to Alkynes.CHINESE JOURNAL OF ORGANIC CHEMISTRY,37(2),284-300.
MLA	Zhao Fei,et al."Research Progress in Metal-Catalyzed Addition of Carbon-Hetero Bonds to Alkynes".CHINESE JOURNAL OF ORGANIC CHEMISTRY 37.2(2017):284-300.