Regio-selective and stereo-selective hydrosilylation of internal alkynes catalyzed by ruthenium complexes

doi:10.1039/c8ra04083d

	Regio-selective and stereo-selective hydrosilylation of internal alkynes catalyzed by ruthenium complexes
	Dai, Wenhao 1,2; Wu, Xiaowei 1,3; Li, Chunpu 1; Zhang, Rui 1,3; Wang, Jiang1 ; Liu, Hong1,2
刊名	RSC ADVANCES
	2018
卷号	8 期号:49 页码:28261-28265
ISSN号	2046-2069
DOI	10.1039/c8ra04083d
文献子类	Article
英文摘要	In this study, ruthenium(II)-catalyzed direct hydrosilylation of internal alkynes with high regio-selectivity and stereo-selectivity is reported. This title transformation led to various vinylsilanes in good to excellent yields. This approach features mild reaction conditions, low catalyst loading, air-stability, and good functional group tolerance. Furthermore, gram-scale preparation and some transformations of vinylsilanes were carried out, which further underscored its synthetic utility and applicability.
资助项目	National Natural Science Foundation of China[81620108027] ; National Natural Science Foundation of China[21632008] ; National Natural Science Foundation of China[81602975] ; Major Project of Chinese National Programs for Fundamental Research and Development[2015CB910304]
WOS关键词	Z-SELECTIVE HYDROSILYLATION ; TERMINAL ALKYNES ; TRANS-HYDROMETALATION ; PROPARGYLIC ALCOHOLS ; SILICON ; BONDS ; HYDROSILANES ; 1-ALKYNES ; MECHANISM ; EFFICIENT
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000442078800065
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/272301]
专题	药物化学研究室
通讯作者	Liu, Hong
作者单位	1.Chinese Acad Sci, Shanghai Inst Mat Med, Key Lab Receptor Res, 555 Zu Chong Zhi Rd, Shanghai 201203, Peoples R China; 2.China Pharmaceut Univ, Sch Pharm, Nanjing 210009, Jiangsu, Peoples R China; 3.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Dai, Wenhao,Wu, Xiaowei,Li, Chunpu,et al. Regio-selective and stereo-selective hydrosilylation of internal alkynes catalyzed by ruthenium complexes[J]. RSC ADVANCES,2018,8(49):28261-28265.
APA	Dai, Wenhao,Wu, Xiaowei,Li, Chunpu,Zhang, Rui,Wang, Jiang,&Liu, Hong.(2018).Regio-selective and stereo-selective hydrosilylation of internal alkynes catalyzed by ruthenium complexes.RSC ADVANCES,8(49),28261-28265.
MLA	Dai, Wenhao,et al."Regio-selective and stereo-selective hydrosilylation of internal alkynes catalyzed by ruthenium complexes".RSC ADVANCES 8.49(2018):28261-28265.