Vapor triggered fluorescent color changes among solvates of Emodin | |
Li, Meiqi1,2; Zhang, Qi1; He, Hongyan1,2; Wang, Jian-Rong1; Mei, Xuefeng1 | |
刊名 | JOURNAL OF MATERIALS CHEMISTRY C |
2017-06-28 | |
卷号 | 5期号:24页码:5970-5976 |
ISSN号 | 2050-7526 |
DOI | 10.1039/c7tc01593c |
文献子类 | Article |
英文摘要 | The reversible vapochromic phenomenon of Emodin (EM), which is an eco-friendly, naturally occurring and metal-free organic MCL material, was investigated, and six new EM solvates were synthesized. Vapor and mechanical force triggered reversible fluorescent color changes, which occurred during solid-state transition processes, were fully studied. It was found that different types of H-bonds and pi-pi interactions highlighted the reasons why EM solvates exhibited significantly different fluorescent colors. This study provides a new approach to find a vapor sensitive MCL material without metal elements and chemical synthesis. |
资助项目 | National Natural Science Foundation of China[81402898] ; Youth Innovation Promotion Association CAS[2016257] ; CAS Key Technology Talent Program[00000000] ; SANOFI-SIBS Scholarship[00000000] |
WOS关键词 | SOLID-STATE LUMINESCENCE ; ORGANIC-CRYSTALS ; EMISSION ; VAPOCHROMISM ; PACKING ; POLYMORPHS |
WOS研究方向 | Materials Science ; Physics |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000404071600017 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.183/handle/2S10ELR8/272598] |
专题 | 药物质量控制与固体化学研究中心 |
通讯作者 | Mei, Xuefeng |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, Pharmaceut Analyt & Solid State Chem Res Ctr, Shanghai 201203, Peoples R China; 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Meiqi,Zhang, Qi,He, Hongyan,et al. Vapor triggered fluorescent color changes among solvates of Emodin[J]. JOURNAL OF MATERIALS CHEMISTRY C,2017,5(24):5970-5976. |
APA | Li, Meiqi,Zhang, Qi,He, Hongyan,Wang, Jian-Rong,&Mei, Xuefeng.(2017).Vapor triggered fluorescent color changes among solvates of Emodin.JOURNAL OF MATERIALS CHEMISTRY C,5(24),5970-5976. |
MLA | Li, Meiqi,et al."Vapor triggered fluorescent color changes among solvates of Emodin".JOURNAL OF MATERIALS CHEMISTRY C 5.24(2017):5970-5976. |
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