A copper-based layered coordination polymer: synthesis, magnetic properties and electrochemical performance in supercapacitors

doi:10.1039/c5dt02918j

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	A copper-based layered coordination polymer: synthesis, magnetic properties and electrochemical performance in supercapacitors
	Liu, Qi 1,2,3; Liu, Xiuxiu 1,2; Shi, Changdong 1,2; Zhang, Yanpeng 1,2; Feng, Xuejun 1,2; Cheng, Mei-Ling 1,2; Su, Seng 1,2; Gu, Jiande4
刊名	DALTON TRANSACTIONS
	2015
卷号	44 期号:44 页码:19175-19184
ISSN号	1477-9226
DOI	10.1039/c5dt02918j
文献子类	Article
英文摘要	A copper-based layered coordination polymer ([Cu(hmt)(tfbdc)(H2O)]; hmt = hexamethylenetetramine, tfbdc = 2,3,5,6-tetrafluoroterephthalate; Cu-LCP) has been synthesized, and it has been structurally and magnetically characterized. The Cu-LCP shows ferromagnetic interactions between the adjacent copper(II) ions. Density functional theory calculations on the special model of Cu-LCP support the occurrence of ferromagnetic interactions. As an electrode material for supercapacitors, Cu-LCP exhibits a high specific capacitance of 1274 F g(-1) at a current density of 1 A g(-1) in 1 M LiOH electrolyte, and the capacitance retention is about 88% after 2000 cycles.
资助项目	National Natural Science Foundation of China[20671045] ; National Natural Science Foundation of China[20971060] ; National Natural Science Foundation of China[21101018] ; Priority Academic Program Development of Jiangsu Higher Education Institutions[00000000] ; Natural Science Foundation of State Key Laboratory of Coordination Chemistry[00000000]
WOS关键词	METAL-ORGANIC-FRAMEWORKS ; CRYSTAL-STRUCTURE ; BRIDGING LIGAND ; ENERGY-STORAGE ; AB-INITIO ; COMPLEXES ; TETRAFLUOROTEREPHTHALATE ; HEXAMETHYLENETETRAMINE ; ELECTRODE ; TRANSITION
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000364146400016
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/276691]
专题	药物发现与设计中心中科院受体结构与功能重点实验室新药研究国家重点实验室
通讯作者	Liu, Qi
作者单位	1.Changzhou Univ, Sch Petrochem Engn, Changzhou 213164, Peoples R China; 2.Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China; 3.Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China; 4.Chinese Acad Sci, Drug Design & Discovery Ctr, Shanghai Inst Mat Med, State Key Lab Drug Res,Shanghai Inst Biol Sci, Shanghai 201203, Peoples R China
推荐引用方式 GB/T 7714	Liu, Qi,Liu, Xiuxiu,Shi, Changdong,et al. A copper-based layered coordination polymer: synthesis, magnetic properties and electrochemical performance in supercapacitors[J]. DALTON TRANSACTIONS,2015,44(44):19175-19184.
APA	Liu, Qi.,Liu, Xiuxiu.,Shi, Changdong.,Zhang, Yanpeng.,Feng, Xuejun.,...&Gu, Jiande.(2015).A copper-based layered coordination polymer: synthesis, magnetic properties and electrochemical performance in supercapacitors.DALTON TRANSACTIONS,44(44),19175-19184.
MLA	Liu, Qi,et al."A copper-based layered coordination polymer: synthesis, magnetic properties and electrochemical performance in supercapacitors".DALTON TRANSACTIONS 44.44(2015):19175-19184.