First observation of a self-assembled two-layer trinuclear Schiff base complex of d-f metal ions connected with mu-imine nitrogen and mu-formyl oxygen atoms

	First observation of a self-assembled two-layer trinuclear Schiff base complex of d-f metal ions connected with mu-imine nitrogen and mu-formyl oxygen atoms
	Kong, DY ; Zhai, YF ; Zhuang, MQ ; Li, Q ; Xie, YY; Huang, XY
刊名	SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
	2000-07
卷号	30 期号:6 页码:1057-1068
ISSN号	0094-5714
文献子类	Article
英文摘要	The synthesis and structural characterization of a trinuclear Schiff base complex with a Cu2Dy (Dy = dysprosium) core is reported for the first time. The crystal data for [C42H40N6O12C13Cu2Dy]. 6H(2)O (2) are as follows: orthorhombic, space group Pbcn (#60), Z = 4, a = 12.476(5) Angstrom, b = 26.522(5) Angstrom, c = 15.028(5) Angstrom, V = 4973(1) Angstrom(3), F(000) = 2608, Dc = 1.748 gcm(-3), mu(Mo-K alpha) = 3.37 mm(-1), T = 296 K and 2130 reflections were observed with [I>2 sigma(I)]. The refinement converged with R = 0.089, Rw = 0.086 and S = 1.40. The coordinate polyhedron of the central metal Dy(III) and Cu(II) atoms is an eight-coordinated trigonal-dodecahedrone and a five-coordinated square-pyramid, respectively.
WOS关键词	CRYSTAL-STRUCTURE ; MACROCYCLIC LIGANDS ; LANTHANIDES ; ACTINIDES ; BEHAVIOR ; DESIGN
WOS研究方向	Chemistry
语种	英语
出版者	MARCEL DEKKER INC
WOS记录号	WOS:000088184500007
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/274604]
专题	中国科学院上海药物研究所
通讯作者	Kong, DY
作者单位	1.Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA 2.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 200031, Peoples R China 3.Rutgers State Univ, Dept Chem, Camden, NJ 08102 USA
推荐引用方式 GB/T 7714	Kong, DY,Zhai, YF,Zhuang, MQ,et al. First observation of a self-assembled two-layer trinuclear Schiff base complex of d-f metal ions connected with mu-imine nitrogen and mu-formyl oxygen atoms[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY,2000,30(6):1057-1068.
APA	Kong, DY,Zhai, YF,Zhuang, MQ,Li, Q,Xie, YY,&Huang, XY.(2000).First observation of a self-assembled two-layer trinuclear Schiff base complex of d-f metal ions connected with mu-imine nitrogen and mu-formyl oxygen atoms.SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY,30(6),1057-1068.
MLA	Kong, DY,et al."First observation of a self-assembled two-layer trinuclear Schiff base complex of d-f metal ions connected with mu-imine nitrogen and mu-formyl oxygen atoms".SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY 30.6(2000):1057-1068.