Fluoroborophosphates: a family of potential deep ultraviolet NLO materials

doi:10.1039/c9qi00006b

	Fluoroborophosphates: a family of potential deep ultraviolet NLO materials
	Wu, Baolin; Hu, Chunli; Tang, Ruling; Mao, Feifei; Feng, Jianghe; Mao, Jianggao
刊名	INORGANIC CHEMISTRY FRONTIERS
	2019-03-01
卷号	6 期号:3 页码:723
ISSN号	2052-1553
DOI	10.1039/c9qi00006b
文献子类	Article
英文摘要	A series of new acentric fluoroborophosphates, namely, RbBPO4F, CsBPO4F and (NH4)(2)BPO4F2, have been obtained by combining BO3F or BO2F2 with a PO4 tetrahedron. The structures of the isomeric RbBPO4F and CsBPO4F feature a three-dimensional diamond framework, in which a BO3F (or PO4) tetrahedron corner is shared with three PO4 (or BO3F) tetrahedra, forming 1D tunnels of eight-membered rings (MRs) along the three axial directions, which are filled with alkali cations. (NH4)(2)BPO4F2 exhibits a 3D supramolecular structure, in which 1D [BPO4F2](infinity)(1) anionic chains along the a axes based on corner-sharing and alternating PO4 and BO2F2 tetrahedra are further interconnected with ammonium cations by electrostatic attractions and hydrogen bonds. RbBPO4F, CsBPO4F and (NH4)(2)BPO4F2 display second-harmonic generation (SHG) signals approximately 0.4, 0.6 and 0.8 times that of KH2PO4 (KDP) and exhibit short UV absorption edges (< 200 nm). Measurements of thermal stability and optical properties and theoretical calculations have also been performed.
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/27298]
专题	中国科学院上海硅酸盐研究所
推荐引用方式 GB/T 7714	Wu, Baolin,Hu, Chunli,Tang, Ruling,et al. Fluoroborophosphates: a family of potential deep ultraviolet NLO materials[J]. INORGANIC CHEMISTRY FRONTIERS,2019,6(3):723.
APA	Wu, Baolin,Hu, Chunli,Tang, Ruling,Mao, Feifei,Feng, Jianghe,&Mao, Jianggao.(2019).Fluoroborophosphates: a family of potential deep ultraviolet NLO materials.INORGANIC CHEMISTRY FRONTIERS,6(3),723.
MLA	Wu, Baolin,et al."Fluoroborophosphates: a family of potential deep ultraviolet NLO materials".INORGANIC CHEMISTRY FRONTIERS 6.3(2019):723.