Corrosion behavior of Ni-Al alloys beneath chlorides melt salt at 700 degrees C
Guo, LL; Yue, Y; Pan, TJ; Tang, ZF; Liu, W
刊名SOLAR ENERGY
2019
卷号184期号:-页码:657—663
关键词HIGH-TEMPERATURE CORROSION FE-CR HOT CORROSION ZNCL2-KCL DEGRADATION DEPOSITS STEELS
ISSN号0038-092X
DOI10.1016/j.solener.2019.04.045
文献子类期刊论文
英文摘要Corrosion behavior of the binary Ni-xAl alloys (x = 6, 10, and 15 at.%) is comparatively studied in pure oxygen with and without a ZnCl2-KCl melt deposit at 700 degrees C. The oxidation of all alloys in oxygen atmosphere is strongly accelerated by ZnCl2-KCl deposits, with the formation of porous oxide scales and internal attack of the matrix induced by chlorine. The corrosion resistance of Ni-Al alloys under these present corrosion conditions is improved with increasing aluminum content of alloys, which is ascribed to the formation of alumina in the inner layer of corrosion products. The effect of aluminum is attributed to the increasing of the Al2O3 content in the oxide scales, which may act as barrier to prevent the rapid migration of the reactants through the oxides film layer. A mechanism accounting for the accelerated corrosion of Ni-Al alloys beneath ZnCl2-KCl deposits is regarded as a result of the combination of electrochemical reactions and active oxidation under mixed chlorides deposits.
语种英语
内容类型期刊论文
源URL[http://ir.sinap.ac.cn/handle/331007/31532]  
专题上海应用物理研究所_中科院上海应用物理研究所2011-2017年
作者单位1.Lawrence Berkeley Natl Lab, Energy Storage & Distributed Resources Div, Berkeley, CA 94720 USA;
2.Changzhou Univ, Jiangsu Collaborat Innovat Ctr Photovol aic Sci &, Jiangsu Key Lab Mat Surface Technol, Natl Expt Demonstrat Ctr Mat Sci & Engn,Sch Mat S, Changzhou 213164, Peoples R China;
3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
推荐引用方式
GB/T 7714
Guo, LL,Yue, Y,Pan, TJ,et al. Corrosion behavior of Ni-Al alloys beneath chlorides melt salt at 700 degrees C[J]. SOLAR ENERGY,2019,184(-):657—663.
APA Guo, LL,Yue, Y,Pan, TJ,Tang, ZF,&Liu, W.(2019).Corrosion behavior of Ni-Al alloys beneath chlorides melt salt at 700 degrees C.SOLAR ENERGY,184(-),657—663.
MLA Guo, LL,et al."Corrosion behavior of Ni-Al alloys beneath chlorides melt salt at 700 degrees C".SOLAR ENERGY 184.-(2019):657—663.
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