Bottom-Up Preparation of Fully sp(2)-Bonded Porous Carbons with High Photoactivities

doi:10.1002/adfm.201808423

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Bottom-Up Preparation of Fully sp(2)-Bonded Porous Carbons with High Photoactivities
	Ming, WY ; Bi, S ; Zhang, YH ; Yu, KJ ; Lu, CB ; Fu, XB ; Qiu, F ; Liu, P ; Su, YZ ; Zhang, F
刊名	ADVANCED FUNCTIONAL MATERIALS
	2019
卷号	29 期号:14 页码:—
关键词	CONJUGATED MICROPOROUS POLYMERS COVALENT ORGANIC POLYMER PHOTOCATALYTIC DEGRADATION SOLAR-CELLS AZO DYES EFFICIENT WATER STORAGE HETEROSTRUCTURES NANOSTRUCTURES
ISSN号	1616-301X
DOI	10.1002/adfm.201808423
文献子类	期刊论文
英文摘要	Porous carbons, possessing exceptional stability, high surface area, and electric conductivity, are broadly used as superior adsorbent, supporter, or electrode material for environmental protection, industrial catalysis, and energy storage and conversion. The construction of such kinds of materials with designable structures and properties will extremely extend their potential applications, but remains a huge synthetic challenge. Herein, a bottom-up approach is presented to synthesize one type of fully sp(2 )carbon-bonded frameworks by transition metal-catalyzed cross-coupling of different polyphenylenes with electron-withdrawing 9,9'-bifluorenylidene (9,9'-BF) through its 2,7-position. The resulting porous polymeric carbons exhibit substantial semiconducting properties, such as strong light-harvesting capabilities in the visible light region, likely due to their pi-extended backbones with donor-acceptor characters. Their electronic and porous structures can be finely tuned via the polyphenylene spacers. The intriguing properties allow these porous carbons to efficiently catalyze dye degradation under visible light or even natural sunlight with high reusability. Meanwhile, associated with their intrinsic structures, these porous carbons also exhibit highly selective degradation activities toward different dyes. In particular, the photodegradation mechanism involving oxygen and electron is elucidated for the first time for such kinds of materials, related to the presence of specific 9,9'-BF units in their pi-conjugated skeletons.
语种	英语
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/31493]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
作者单位	1.Shanghai Jiao Tong Univ, Sch Aeronaut & Astronaut, Shanghai 200240, Peoples R China; 2.Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China; 3.Shanghai Jiao Tong Univ, Sch Elect Informat & Elect Engn, Shanghai 200240, Peoples R China; 4.Chinese Acad Sci, Shanghai Inst Appl Phys, Dept Molten Salt Chem & Engn, Shanghai 201800, Peoples R China; 5.Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China; 6.Univ Bristol, Sch Chem, Bristol BS8 ITS, Avon, England
推荐引用方式 GB/T 7714	Ming, WY,Bi, S,Zhang, YH,et al. Bottom-Up Preparation of Fully sp(2)-Bonded Porous Carbons with High Photoactivities[J]. ADVANCED FUNCTIONAL MATERIALS,2019,29(14):—.
APA	Ming, WY.,Bi, S.,Zhang, YH.,Yu, KJ.,Lu, CB.,...&Zhang, F.(2019).Bottom-Up Preparation of Fully sp(2)-Bonded Porous Carbons with High Photoactivities.ADVANCED FUNCTIONAL MATERIALS,29(14),—.
MLA	Ming, WY,et al."Bottom-Up Preparation of Fully sp(2)-Bonded Porous Carbons with High Photoactivities".ADVANCED FUNCTIONAL MATERIALS 29.14(2019):—.