Durable Anti-Superbug Polymers: Covalent Bonding of Ionic Liquid onto the Polymer Chains | |
Guan, JP; Wang, YY; Wu, SL; Li, YJ; Li, JY | |
刊名 | BIOMACROMOLECULES |
2017 | |
卷号 | 18期号:12页码:4364-4372 |
关键词 | POLY(VINYLIDENE FLUORIDE) ANTIMICROBIAL MEMBRANES SENSITIVE MEMBRANES BACTERIA NANOPARTICLES COPOLYMERS SURFACE SILVER NANOCOMPOSITES MECHANISM |
ISSN号 | 1525-7797 |
DOI | 10.1021/acs.biomac.7b01416 |
文献子类 | 期刊论文 |
英文摘要 | Here, we fabricated the ionic liquid (IL) grafted poly(vinylidene fluoride) (PVDF) (PVDF-g-IL,) via electron-beam irradiation to fight common bacteria and multidrug-resistant "superbugs". Two types of ILs, 1-vinyl-3-butylimmidazolium chloride (IL (Cl)) and 1-vinyl-3-ethylimidazolium tetrafluoroborate (IL (BF4)), were used. It was found that the PVDF-g-IL exhibited superior antibacterial performance, with almost the same mechanical and thermal performance as unmodified PVDF. Nonwovens and films made from PVDF-g-IL materials exhibited broad-spectrum antimicrobial activity against common bacteria and "superbugs" with the strong electrostatic interactions between ILs and microbial cell membranes. With extremely low IL loading (0.05 wt %), the cell reduction of PVDF-g-IL (Cl) nonwovens improved from 0.2 to 4.4 against S. aureus. Moreover, the antibacterial activity of PVDF-g-IL nonwovens was permanent for the covalent bonds between ILs and polymer chains. The work provides a simple strategy to immobilize ionic antibacterial agents onto polymer substrates, which may have great potential applications in healthcare and household applications. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.sinap.ac.cn/handle/331007/30910] |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Appl Phys, 2019 Jialuo Rd, Shanghai 201800, Peoples R China 3.Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, 16 Xuelin Rd, Hangzhou 310036, Zhejiang, Peoples R China |
推荐引用方式 GB/T 7714 | Guan, JP,Wang, YY,Wu, SL,et al. Durable Anti-Superbug Polymers: Covalent Bonding of Ionic Liquid onto the Polymer Chains[J]. BIOMACROMOLECULES,2017,18(12):4364-4372. |
APA | Guan, JP,Wang, YY,Wu, SL,Li, YJ,&Li, JY.(2017).Durable Anti-Superbug Polymers: Covalent Bonding of Ionic Liquid onto the Polymer Chains.BIOMACROMOLECULES,18(12),4364-4372. |
MLA | Guan, JP,et al."Durable Anti-Superbug Polymers: Covalent Bonding of Ionic Liquid onto the Polymer Chains".BIOMACROMOLECULES 18.12(2017):4364-4372. |
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