Carbon dioxide electroreduction over imidazolate ligands coordinated with Zn(II) center in ZIFs

doi:10.1016/j.nanoen.2018.07.047

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Carbon dioxide electroreduction over imidazolate ligands coordinated with Zn(II) center in ZIFs
	Jiang, XL ; Li, HB ; Xiao, JP ; Gao, DF ; Si, R ; Yang, F ; Li, YS ; Wang, GX ; Bao, XH
刊名	NANO ENERGY
	2018
卷号	52 期号:-页码:345-350
关键词	METAL-ORGANIC FRAMEWORKS SELECTIVE ELECTROCATALYTIC REDUCTION MOLECULAR-SIEVING MEMBRANES ELECTROCHEMICAL REDUCTION CO2 REDUCTION AU NANOPARTICLES EFFICIENT OXIDE NANOSHEETS CATALYSTS
ISSN号	2211-2855
DOI	10.1016/j.nanoen.2018.07.047
文献子类	期刊论文
英文摘要	Metal-organic frameworks (MOFs), combining the favorable characteristics of heterogeneous and homogeneous catalysts, have been explored as a novel class of model catalytic materials for understanding electrochemical CO2 reduction reaction (CO2RR). MOFs exhibit high Faradaic efficiency of CO2RR, but suffer from limited current density of CO2RR (typically lower than 3.4 mA cm(-2)). Herein, we investigate zeolitic imidazolate frameworks (ZIFs) including ZIF-8, ZIF-108, ZIF-7 and SIM-1 with the same SOD (sodalite) topology and different organic ligands for CO2RR in aqueous electrolyte. ZIF-8 shows the highest CO Faradaic efficiency of 81.0% at - 1.1 V (vs. reversible hydrogen electrode, RHE) among the four ZIF catalysts, and the highest CO current density can reach 12.8 mA cm(-2) at - 1.3 V (vs. RHE) over ZIF-108. In situ X-ray absorption spectroscopy measurements and density functional theory calculations indicate that the imidazolate ligands coordinated with the Zn(II) center in ZIFs are the active sites for CO2RR, determining the CO Faradaic efficiency and current density over ZIFs.
语种	英语
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/30870]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
作者单位	1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis,Ctr Excellence Nanosci, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 4.Westlake Univ, Inst Nat Sci, Westlake Inst Adv Study, Hangzhou 310024, Zhejiang, Peoples R China 5.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China 6.Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China 7.Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China
推荐引用方式 GB/T 7714	Jiang, XL,Li, HB,Xiao, JP,et al. Carbon dioxide electroreduction over imidazolate ligands coordinated with Zn(II) center in ZIFs[J]. NANO ENERGY,2018,52(-):345-350.
APA	Jiang, XL.,Li, HB.,Xiao, JP.,Gao, DF.,Si, R.,...&Bao, XH.(2018).Carbon dioxide electroreduction over imidazolate ligands coordinated with Zn(II) center in ZIFs.NANO ENERGY,52(-),345-350.
MLA	Jiang, XL,et al."Carbon dioxide electroreduction over imidazolate ligands coordinated with Zn(II) center in ZIFs".NANO ENERGY 52.-(2018):345-350.