Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids

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	Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids
	Deng YQ(邓友全); Deng YQ(邓友全); Zhang QH(张庆华); Shi F(石峰)
刊名	Journal of Molecular Catalysis A: Chemical
	2007
卷号	271 页码:89-92
关键词	Green chemistry Ionic liquid Carbamates Amine Non-phosgene
ISSN号	1381-1169
通讯作者	邓友全
中文摘要	Selective synthesis of carbamates from amines and dimethyl carbonate were studied in the presence of various ionic liquids as catalysts. The –SO3H-functionalized ionic liquid was found to be the most active catalyst among the applied ionic liquids, and nearly 100% conversion and 95% selectivity were achieved when using 1,6-hexanediamine as reactant. The acid functional ionic liquid catalyst system is also readily separable and reusable after reaction.
学科主题	物理化学
收录类别	SCI
资助信息	National Natural Science Foundation of China (Nos. 20225309;20533080)
语种	英语
WOS记录号	WOS:000246908500016
公开日期	2013-08-20
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/3652]
专题	兰州化学物理研究所_绿色化学研究发展中心
通讯作者	Deng YQ(邓友全); Deng YQ(邓友全)
推荐引用方式 GB/T 7714	Deng YQ,Deng YQ,Zhang QH,et al. Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids[J]. Journal of Molecular Catalysis A: Chemical,2007,271:89-92.
APA	邓友全,邓友全,张庆华,&石峰.(2007).Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids.Journal of Molecular Catalysis A: Chemical,271,89-92.
MLA	邓友全,et al."Synthesis of carbamates from aliphatic amines and dimethyl carbonate catalyzed by acid functional ionic liquids".Journal of Molecular Catalysis A: Chemical 271(2007):89-92.