Enhanced tribology durability of a self-assembled monolayer of alkylphosphonic acid on a textured copper substrate
Wan Y(万勇)1; Wang YH(王银虎)1; Zhang Q(张全)1; Wang ZQ(王忠乾)1; Xu Z(许震)1; Liu ZS(刘长松)1; Zhang JY(张俊彦)2
刊名Applied Surface Science
2012
卷号259页码:147-152
关键词Thin film Friction Self-assembled monolayer Chemical etching Copper
ISSN号0169-4332
通讯作者万勇
英文摘要A simple two-step process was developed to render the copper surface with lower friction and long durability. The copper substrate was immersed in a 0.01 M NaOH solution to fabricate a textured Cu2O film. A self-assembled monolayer of alkylphosphonic acid was then deposited on the Cu2O film to acquire high hydrophobicity. Scanning electron microscopy, Fourier transform infrared microscopy and water contact angle measurements were used to analyze the morphological features, the chemical composition and hydrophobicity of freshly prepared samples, respectively. Moreover, the friction-reducing behavior of the organic-inorganic composite film sliding against steel was evaluated in a ball-on-plate configuration. It was found that the alkylphosphonic acid films on the textured Cu2O film led to decreased friction with significantly extended life. For a constant load, the increase in chain length of alkylphosphonic acid yields the films that are dramatically more stable against tribological deformation and provide low coefficients of friction over much longer periods of time.
学科主题材料科学与物理化学
收录类别SCI
资助信息the Natural Science Foundation of Shandong Province (Y2008F05);the Applied and Basic Research Foundation of Qingdao City (09-1-3-35-jch)
语种英语
WOS记录号WOS:000310436900024
公开日期2013-07-12
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/3296]  
专题兰州化学物理研究所_固体润滑国家重点实验室
作者单位1.Qingdao Technol Univ, Sch Mech Engn, Qingdao 266033, Peoples R China
2.Chinese Acad Sci, State Key Lab Solid Lubricat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Wan Y,Wang YH,Zhang Q,et al. Enhanced tribology durability of a self-assembled monolayer of alkylphosphonic acid on a textured copper substrate[J]. Applied Surface Science,2012,259:147-152.
APA Wan Y.,Wang YH.,Zhang Q.,Wang ZQ.,Xu Z.,...&Zhang JY.(2012).Enhanced tribology durability of a self-assembled monolayer of alkylphosphonic acid on a textured copper substrate.Applied Surface Science,259,147-152.
MLA Wan Y,et al."Enhanced tribology durability of a self-assembled monolayer of alkylphosphonic acid on a textured copper substrate".Applied Surface Science 259(2012):147-152.
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