Efficient Chiral Monophosphorus Ligands for Asymmetric Suzuki-Miyaura Coupling Reactions

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	Efficient Chiral Monophosphorus Ligands for Asymmetric Suzuki-Miyaura Coupling Reactions
	Tang WJ(汤文军) ; PATEL NITINCHANDRA D ; Xu GQ(徐广庆) ; Xu XB(徐晓冰) ; SAVOIE JOLAINE ; MA SHENGLI ; HAO MINGHONG ; KESHIPEDDY SANTOSH ; CAPACCI ANDREW G ; WEI XUDONG ; ZHANG YONGDA ; GAO JOE J ; LI WENJIE ; RODRIGUEZ SONIA ; LU BRUCE Z ; YEE NATHAN K ; SENANAYAKE CHRIS H
刊名	Org. Lett.
	2012
卷号	14 期号:9 页码:2258-2261
ISSN号	1523-7060
其他题名	高效手性单膦配体在不对称Suzuki-Miyaura偶联反应中的应用
通讯作者	汤文军
英文摘要	A series of novel P-chiral monophosphorus ligands exhibit efficiency in asymmetric Suzuki-Miyaura coupling reactions, enabling the construction of an array of chiral biaryl products In high yields and excellent enantioselectivities (up to 96% ee) under mild conditions. The carbonyl-benzooxazolidinone moiety in these chiral biaryl products allows facile derivatization for further synthetic applications. A computational study has revealed that a pi-pi interaction between the two coupling partners can enhance the enantioselectivity of the coupling reaction.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol300659d
语种	英语
WOS记录号	WOS:000303492200017
公开日期	2013-08-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/27987]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Tang WJ,PATEL NITINCHANDRA D,Xu GQ,et al. Efficient Chiral Monophosphorus Ligands for Asymmetric Suzuki-Miyaura Coupling Reactions[J]. Org. Lett.,2012,14(9):2258-2261.
APA	汤文军.,PATEL NITINCHANDRA D.,徐广庆.,徐晓冰.,SAVOIE JOLAINE.,...&SENANAYAKE CHRIS H.(2012).Efficient Chiral Monophosphorus Ligands for Asymmetric Suzuki-Miyaura Coupling Reactions.Org. Lett.,14(9),2258-2261.
MLA	汤文军,et al."Efficient Chiral Monophosphorus Ligands for Asymmetric Suzuki-Miyaura Coupling Reactions".Org. Lett. 14.9(2012):2258-2261.