effectsofdopingfecl3onhydrogenstoragepropertiesoflinhsystem

	effectsofdopingfecl3onhydrogenstoragepropertiesoflinhsystem
	Zhang Weijin 2; Wang Han 2; Cao Hujun 1; He Teng 2; Guo Jianping 2; Wu Guotao 2; Chen Ping 2
刊名	progressinnaturalsciencematerialsinternational
	2017-01-01
卷号	27 期号:1 页码:139
ISSN号	1002-0071
英文摘要	The effects of doping fecl3 on the linh2- 2lih system were investigated systematically. fecl(3)was prior to react with lih during ball milling their mixtures. the metallic fe, which is generated from metathesis reaction between fecl3 and lih, plays an important role on improving the dehydrogenation kinetics of linh2-2lih system. the results indicated that the dehydrogenation peak and ending temperatures of the doped 1 mol% fecl3 sample shifted to low temperatures, and the dehydrogenation active energy changed from 102.45 kj/mol to 87.52 kj/mol. while increasing the amount of fecl3, an excess of licl, the by-product of metathesis reaction between fecl3 and lih, can stabilize linh2 and thus hinder hydrogen desorption. the dehydrogenation product is a new solid cubic phase solution of lithium imide-chloride. the high limit of the solid solution of licl and li2nh is near the molar ratio of 1:1.
语种	英语
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/177616]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Institute of Materials Research, Materials Technology, Helmholtz-Zentrum Geesthacht 2.中国科学院大连化学物理研究所
推荐引用方式 GB/T 7714	Zhang Weijin,Wang Han,Cao Hujun,et al. effectsofdopingfecl3onhydrogenstoragepropertiesoflinhsystem[J]. progressinnaturalsciencematerialsinternational,2017,27(1):139.
APA	Zhang Weijin.,Wang Han.,Cao Hujun.,He Teng.,Guo Jianping.,...&Chen Ping.(2017).effectsofdopingfecl3onhydrogenstoragepropertiesoflinhsystem.progressinnaturalsciencematerialsinternational,27(1),139.
MLA	Zhang Weijin,et al."effectsofdopingfecl3onhydrogenstoragepropertiesoflinhsystem".progressinnaturalsciencematerialsinternational 27.1(2017):139.