singleatomcatalysisbridgingthehomoandheterogeneouscatalysis

	singleatomcatalysisbridgingthehomoandheterogeneouscatalysis
	Chen Fang; Jiang Xunzhu; Zhang Leilei; Lang Rui; Qiao Botao
刊名	chinesejournalofcatalysis
	2018-01-01
卷号	39 期号:5 页码:893
ISSN号	0253-9837
英文摘要	Single-atom catalysis, the catalysis by single-atom catalysts (sacs), has attracted considerable attention in recent years as a new frontier in the heterogeneous catalysis field. sacs have the advantages of both homogeneous catalysts (isolated active sites) and heterogeneous catalysts (stable and easy to separate), and are thus predicted to be able to bridge the homo- and heterogeneous catalysis. this prediction was first experimentally demonstrated in 2016. in this mini-review, we summarize the few homogeneous catalysis progresses reported recently where sacs have exhibited promising application: a) rh/zno and rh/coo sac have been used successfully in hydroformylation of olefin of which the activity are comparable to the homogeneous wilkinson's catalyst; b) a pt/al2o3 sac has shown excellent performance in hydrosilylation reaction; and c) m-n-c sacs (m = fe, co etc.) have been applied in the activation of c-h bonds. all of these examples suggest that fabrication of suitable sacs could provide a new avenue for the heterogenization of homogeneous catalysts. these pioneering works shed new light on the recognition of single-atom catalysis in bridging the homo- and heterogeneous catalysis. (c) 2018, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved.
语种	英语
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/176009]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	中国科学院大连化学物理研究所
推荐引用方式 GB/T 7714	Chen Fang,Jiang Xunzhu,Zhang Leilei,et al. singleatomcatalysisbridgingthehomoandheterogeneouscatalysis[J]. chinesejournalofcatalysis,2018,39(5):893.
APA	Chen Fang,Jiang Xunzhu,Zhang Leilei,Lang Rui,&Qiao Botao.(2018).singleatomcatalysisbridgingthehomoandheterogeneouscatalysis.chinesejournalofcatalysis,39(5),893.
MLA	Chen Fang,et al."singleatomcatalysisbridgingthehomoandheterogeneouscatalysis".chinesejournalofcatalysis 39.5(2018):893.