Palladium-Catalyzed Oxidative Cross-Coupling of Conjugated Enynones with Allylarenes: Synthesis of Furyl-Substituted 1,3-Dienes

doi:10.1021/acs.joc.9b00922

	Palladium-Catalyzed Oxidative Cross-Coupling of Conjugated Enynones with Allylarenes: Synthesis of Furyl-Substituted 1,3-Dienes
	Ping, Yifan 1; Zhang, Sudong 1; Chang, Taiwei 1; Wang, Jianbo 1,2
刊名	JOURNAL OF ORGANIC CHEMISTRY
	2019-06-21
卷号	84 期号:12 页码:8275-8283
ISSN号	0022-3263
DOI	10.1021/acs.joc.9b00922
通讯作者	Wang, Jianbo(wangjb@pku.edu.cn)
英文摘要	A new method for the synthesis of furyl-substituted 1,3-dienes via palladium-catalyzed oxidative cross coupling of conjugated enynones with allylarenes is developed. This reaction shows broad substrate scope and good functional group tolerance. Palladium carbene migratory insertion is proposed as the key step for this transformation with conjugated enynones serving as the carbene precursors.
资助项目	National Basic Research Program of China (973 Program)[2015CB856600] ; NSFC[21871010]
WOS关键词	ENE-YNE-KETONES ; C-H AMINATION ; SERIAL LIGAND CATALYSIS ; METAL CARBENE ; TERMINAL ALKENES ; DIAZO-COMPOUNDS ; ALLYL HALIDES ; OLEFINS ; TOSYLHYDRAZONES ; ALKYLATION
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000473116200068
资助机构	National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; NSFC ; NSFC ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; NSFC ; NSFC ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; NSFC ; NSFC ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; NSFC ; NSFC
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/175341]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Jianbo
作者单位	1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Ping, Yifan,Zhang, Sudong,Chang, Taiwei,et al. Palladium-Catalyzed Oxidative Cross-Coupling of Conjugated Enynones with Allylarenes: Synthesis of Furyl-Substituted 1,3-Dienes[J]. JOURNAL OF ORGANIC CHEMISTRY,2019,84(12):8275-8283.
APA	Ping, Yifan,Zhang, Sudong,Chang, Taiwei,&Wang, Jianbo.(2019).Palladium-Catalyzed Oxidative Cross-Coupling of Conjugated Enynones with Allylarenes: Synthesis of Furyl-Substituted 1,3-Dienes.JOURNAL OF ORGANIC CHEMISTRY,84(12),8275-8283.
MLA	Ping, Yifan,et al."Palladium-Catalyzed Oxidative Cross-Coupling of Conjugated Enynones with Allylarenes: Synthesis of Furyl-Substituted 1,3-Dienes".JOURNAL OF ORGANIC CHEMISTRY 84.12(2019):8275-8283.