A Cost-Effective Mixed Matrix Polyethylene Porous Membrane for Long-Cycle High Power Density Alkaline Zinc-Based Flow Batteries

doi:10.1002/adfm.201901674

	A Cost-Effective Mixed Matrix Polyethylene Porous Membrane for Long-Cycle High Power Density Alkaline Zinc-Based Flow Batteries
	Chang, Nana 2,3; Yin, Yanbin 2; Yue, Meng 2,3; Yuan, Zhizhang 2; Zhang, Huamin 1,2; Lai, Qinzhi 2; Li, Xianfeng 1,2
刊名	ADVANCED FUNCTIONAL MATERIALS
	2019-07-01
卷号	29 期号:29 页码:11
关键词	alkaline anti-alkali hollow nanospheres mixed matrix membranes zinc-based flow batteries
ISSN号	1616-301X
DOI	10.1002/adfm.201901674
通讯作者	Lai, Qinzhi(qinzhilai@dicp.ac.cn) ; Li, Xianfeng(lixianfeng@dicp.ac.cn)
英文摘要	Alkaline zinc-based flow batteries (ZFBs) have received considerable interest for renewable energy storage due to their attractive features of low cost and high energy density. However, a membrane with high stability, high selectivity, and high ion conductivity is in urgent need. Herein, an economical mixed matrix membrane with highly anti-alkali microporous hollow spheres (denoted as DM-HM) is developed in this work. With excellent chemical and mechanical stability, DM-HM can achieve a high area capacity of 100 mA h cm(-2) for carbon felt (CF)\|\|Zn@CF symmetrical flow battery, and thereby exhibits 500 stable cycles with a coulombic efficiency of 98.6% and an energy efficiency of 88.3% at 80 mA cm(-2) for alkaline zinc-iron flow battery. Additionally, with 44 wt% of hollow spheres inside matrix, DM-HM can dramatically shorten the ion transport pathway and results in a very high power density battery. A kilowatt stack assembled with DM-HM shows a very impressive performance, further confirming the practicability of this scalable mixed matrix membrane for alkaline ZFBs.
资助项目	China Natural Science Foundation[21206158] ; Key Project of Frontier Science, CAS[QYZDB-SSW-JSC032] ; CAS-DOE collaborative project ; DICPQIBEBT[DICPQIBEBT UN201707] ; DICP[ZZBS201707] ; DICP[ZZBS201814] ; DNL Cooperation Fund of CAS[DNL180307]
WOS关键词	ENERGY-STORAGE ; PERFORMANCE ; ZEOLITE ; ELECTROLYTE
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000478629500022
资助机构	China Natural Science Foundation ; China Natural Science Foundation ; Key Project of Frontier Science, CAS ; Key Project of Frontier Science, CAS ; CAS-DOE collaborative project ; CAS-DOE collaborative project ; DICPQIBEBT ; DICPQIBEBT ; DICP ; DICP ; DNL Cooperation Fund of CAS ; DNL Cooperation Fund of CAS ; China Natural Science Foundation ; China Natural Science Foundation ; Key Project of Frontier Science, CAS ; Key Project of Frontier Science, CAS ; CAS-DOE collaborative project ; CAS-DOE collaborative project ; DICPQIBEBT ; DICPQIBEBT ; DICP ; DICP ; DNL Cooperation Fund of CAS ; DNL Cooperation Fund of CAS ; China Natural Science Foundation ; China Natural Science Foundation ; Key Project of Frontier Science, CAS ; Key Project of Frontier Science, CAS ; CAS-DOE collaborative project ; CAS-DOE collaborative project ; DICPQIBEBT ; DICPQIBEBT ; DICP ; DICP ; DNL Cooperation Fund of CAS ; DNL Cooperation Fund of CAS ; China Natural Science Foundation ; China Natural Science Foundation ; Key Project of Frontier Science, CAS ; Key Project of Frontier Science, CAS ; CAS-DOE collaborative project ; CAS-DOE collaborative project ; DICPQIBEBT ; DICPQIBEBT ; DICP ; DICP ; DNL Cooperation Fund of CAS ; DNL Cooperation Fund of CAS
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/173990]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Lai, Qinzhi; Li, Xianfeng
作者单位	1.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Energy Storage, Zhongshan Rd 457, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Chang, Nana,Yin, Yanbin,Yue, Meng,et al. A Cost-Effective Mixed Matrix Polyethylene Porous Membrane for Long-Cycle High Power Density Alkaline Zinc-Based Flow Batteries[J]. ADVANCED FUNCTIONAL MATERIALS,2019,29(29):11.
APA	Chang, Nana.,Yin, Yanbin.,Yue, Meng.,Yuan, Zhizhang.,Zhang, Huamin.,...&Li, Xianfeng.(2019).A Cost-Effective Mixed Matrix Polyethylene Porous Membrane for Long-Cycle High Power Density Alkaline Zinc-Based Flow Batteries.ADVANCED FUNCTIONAL MATERIALS,29(29),11.
MLA	Chang, Nana,et al."A Cost-Effective Mixed Matrix Polyethylene Porous Membrane for Long-Cycle High Power Density Alkaline Zinc-Based Flow Batteries".ADVANCED FUNCTIONAL MATERIALS 29.29(2019):11.