Rh(i)-Catalyzed intramolecular [2+2+1] cycloaddition of diynes with the N-terminal of the diazo group

doi:10.1039/c9qo00403c

	Rh(i)-Catalyzed intramolecular [2+2+1] cycloaddition of diynes with the N-terminal of the diazo group
	Wang, Bo 2; Wang, Yuankai 2; Wang, Zixuan 2; Wang, Jianbo 1,2
刊名	ORGANIC CHEMISTRY FRONTIERS
	2019-07-21
卷号	6 期号:14 页码:2329-2333
ISSN号	2052-4129
DOI	10.1039/c9qo00403c
通讯作者	Wang, Jianbo(wangjb@pku.edu.cn)
英文摘要	A new type of Rh(i)-catalyzed intramolecular [2 + 2 + 1] cycloaddition of diynes and the N-terminal of a diazo moiety is reported. This study is the first attempt to combine oxidative cyclometallation with carbene migratory insertion. This reaction is suggested to involve the initial oxidative cyclometallation, followed by migratory nitrogen insertion and reductive elimination.
资助项目	973 Program[2015CB856600] ; NSFC[21871010]
WOS关键词	KHAND-TYPE REACTIONS ; PAUSON-KHAND ; METAL CARBENE ; CO SURROGATE ; TOSYLHYDRAZONES ; FUNCTIONALIZATION ; FORMALDEHYDE ; CYCLIZATION ; COUPLINGS ; INSERTION
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000477946500002
资助机构	973 Program ; 973 Program ; NSFC ; NSFC ; 973 Program ; 973 Program ; NSFC ; NSFC ; 973 Program ; 973 Program ; NSFC ; NSFC ; 973 Program ; 973 Program ; NSFC ; NSFC
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/173812]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Jianbo
作者单位	1.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Wang, Bo,Wang, Yuankai,Wang, Zixuan,et al. Rh(i)-Catalyzed intramolecular [2+2+1] cycloaddition of diynes with the N-terminal of the diazo group[J]. ORGANIC CHEMISTRY FRONTIERS,2019,6(14):2329-2333.
APA	Wang, Bo,Wang, Yuankai,Wang, Zixuan,&Wang, Jianbo.(2019).Rh(i)-Catalyzed intramolecular [2+2+1] cycloaddition of diynes with the N-terminal of the diazo group.ORGANIC CHEMISTRY FRONTIERS,6(14),2329-2333.
MLA	Wang, Bo,et al."Rh(i)-Catalyzed intramolecular [2+2+1] cycloaddition of diynes with the N-terminal of the diazo group".ORGANIC CHEMISTRY FRONTIERS 6.14(2019):2329-2333.