Li-Ion solvation in propylene carbonate electrolytes determined by molecular rotational measurements | |
Jiang, Haotian1,2; Zhang, Qi1; Zhang, Yutong1; Sui, Laizhi1; Wu, Guorong1; Yuan, Kaijun1; Yang, Xueming1 | |
刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS |
2019-05-28 | |
卷号 | 21期号:20页码:10417-10422 |
ISSN号 | 1463-9076 |
DOI | 10.1039/c8cp07552b |
通讯作者 | Yuan, Kaijun(kjyuan@dicp.ac.cn) |
英文摘要 | Lithium-ion batteries are an attractive power source for a wide variety of applications. Expanding the performance limit of current Li-ion batteries requires ion-solvent interaction, which governs the ion transport behavior of electrolytes, to be fully understood. We herein examine the coordination number of the Li+ ion in LiPF6-PC solutions using femtosecond vibrational spectroscopy. Surprisingly, we found that the coordination number of PC in the first solvation shell of Li+ decreases from 4 to 2 as the salt concentration increases. At dilute salt concentrations, the Li(PC)(4)(+) complex with a tetrahedral geometry is dominant, while at high salt concentrations, the presence of anions in the first solvation shell modifies the solvation structure, leading only 2 PC molecules to coordinate to Li+ directly. The variety of the solvation structure provides a rational explanation for the ionic conductivity changing as the salt concentration increases. |
资助项目 | National Natural Science Foundation of China (NSFC)[21873099] ; National Natural Science Foundation of China (NSFC)[21673232] ; National Natural Science Foundation of China (NSFC)[21373213] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17000000] ; Chemical Dynamics Research Center[21688102] ; Youth Innovation Promotion Association[2014160] |
WOS关键词 | ETHYLENE CARBONATE ; LITHIUM PERCHLORATE ; LIQUID ELECTROLYTES ; SOLVENT INTERACTION ; LIPF6 ; LIBF4 ; CONDUCTIVITY ; DYNAMICS ; ENERGY |
WOS研究方向 | Chemistry ; Physics |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000476561000016 |
资助机构 | National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Chemical Dynamics Research Center ; Chemical Dynamics Research Center ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Chemical Dynamics Research Center ; Chemical Dynamics Research Center ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Chemical Dynamics Research Center ; Chemical Dynamics Research Center ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Chemical Dynamics Research Center ; Chemical Dynamics Research Center ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/173730] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Yuan, Kaijun |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Liaoning Univ, Dept Phys, 66 Chongshan Rd, Shenyang 110036, Peoples R China |
推荐引用方式 GB/T 7714 | Jiang, Haotian,Zhang, Qi,Zhang, Yutong,et al. Li-Ion solvation in propylene carbonate electrolytes determined by molecular rotational measurements[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2019,21(20):10417-10422. |
APA | Jiang, Haotian.,Zhang, Qi.,Zhang, Yutong.,Sui, Laizhi.,Wu, Guorong.,...&Yang, Xueming.(2019).Li-Ion solvation in propylene carbonate electrolytes determined by molecular rotational measurements.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,21(20),10417-10422. |
MLA | Jiang, Haotian,et al."Li-Ion solvation in propylene carbonate electrolytes determined by molecular rotational measurements".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 21.20(2019):10417-10422. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论