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	The MMCT excited state of a localized mixed valence cyanido- bridged RuII- RuIII; III 2-RuII complex
	Su, Shao-Dong1,2; Zhu, Xiao-Quan1; Zhang, Lin-Tao1,2; Yang, Yu-Ying1,2; Wen, Yue-Hong1; Wu, Xin-Tao1; Yang, Song-Qiu3; Sheng, Tian-Lu1
刊名	DALTON TRANSACTIONS
	2019-07-07
卷号	48期号:25页码:9303-9309
ISSN号	1477-9226
DOI	10.1039/c9dt01503e
通讯作者	Yang, Song-Qiu(sqyang@dicp.ac.cn) ; Sheng, Tian-Lu(tsheng@fjirsm.ac.cn)
英文摘要	To investigate MMCT excited states of MV complexes, two symmetrical tetranuclear cyanido-bridged localized MV complexes (RuCNRuIII)-C-II,III2NCRu(II) have been designed and synthesized. The ultrafast time-resolved transient absorption (TA) spectroscopy experiment reveals that the MMCT rate of 1 and 2 is 0.18 x 10(14) s(-1) (tau = 5.7 x 10(-14) s) and 0.29 x 10(13) s(-1) (tau = 3.46 x 10(-13) s), respectively, which suggests that the MMCT rate or the lifetime of the MMCT excited state may be controlled by a slight change of the substituent group on the metal center.
资助项目	National Science Foundation of China[21773243] ; National Science Foundation of China[21873100] ; 973 Program[2014CB845603] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB20010200]
WOS关键词	PHTHALOCYANINE IRON CENTERS ; ULTRAFAST ELECTRON-TRANSFER ; CRYSTAL-STRUCTURES ; TRANSITION ; REDOX ; CHAINS
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000478066600030
资助机构	National Science Foundation of China ; National Science Foundation of China ; 973 Program ; 973 Program ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Science Foundation of China ; National Science Foundation of China ; 973 Program ; 973 Program ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Science Foundation of China ; National Science Foundation of China ; 973 Program ; 973 Program ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Science Foundation of China ; National Science Foundation of China ; 973 Program ; 973 Program ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/173720]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Yang, Song-Qiu; Sheng, Tian-Lu
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Su, Shao-Dong,Zhu, Xiao-Quan,Zhang, Lin-Tao,et al. The MMCT excited state of a localized mixed valence cyanido- bridged RuII- RuIII; III 2-RuII complex[J]. DALTON TRANSACTIONS,2019,48(25):9303-9309.
APA	Su, Shao-Dong.,Zhu, Xiao-Quan.,Zhang, Lin-Tao.,Yang, Yu-Ying.,Wen, Yue-Hong.,...&Sheng, Tian-Lu.(2019).The MMCT excited state of a localized mixed valence cyanido- bridged RuII- RuIII; III 2-RuII complex.DALTON TRANSACTIONS,48(25),9303-9309.
MLA	Su, Shao-Dong,et al."The MMCT excited state of a localized mixed valence cyanido- bridged RuII- RuIII; III 2-RuII complex".DALTON TRANSACTIONS 48.25(2019):9303-9309.

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