Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines

doi:10.1039/c9ra04836g

	Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines
	Xue, Feng 1; Liu, Qibin 2; Zhu, Yong 1; Qing, Yunfei 1; Wan, Boshun 3
刊名	RSC ADVANCES
	2019-08-18
卷号	9 期号:44 页码:25377-25381
DOI	10.1039/c9ra04836g
通讯作者	Xue, Feng(fxuehist@sina.com) ; Liu, Qibin(qliu@allychem.com) ; Wan, Boshun(bswan@dicp.ac.cn)
英文摘要	An efficient Rh-catalyzed addition of arylboronic acids to N-tosylarylimines has been developed with chiral benzene backbone-based sulfoxide-olefin ligands, where 2-methoxy-1-naphthyl sulfinyl functionalized olefin ligands have shown to be more effective. The versatile method tolerates a wide range of functional groups and shows broad scope without regard to electronic or steric substitution pattern, allowing access to a broad range of chiral diarylmethylamines in high yields (up to 99%) with excellent enantioselectivities (up to 99% ee).
资助项目	National Natural Science Foundation of China[21172218]
WOS关键词	ASYMMETRIC CONJUGATE ADDITION ; ORGANOBORONIC ACIDS ; SULFUR-OLEFINS ; DIENE LIGANDS ; ARYLATION ; CONSTRUCTION ; ACCESS
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000481879400013
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/173288]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Xue, Feng; Liu, Qibin; Wan, Boshun
作者单位	1.Henan Inst Sci & Technol, Coll Chem & Chem Engn, Key Lab Funct Organ Mol Xinxiang City Henan Prov, Xinxiang 453002, Henan, Peoples R China 2.Dalian Allychem Co Ltd, 5 Jinbin Rd, Dalian 116620, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Xue, Feng,Liu, Qibin,Zhu, Yong,et al. Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines[J]. RSC ADVANCES,2019,9(44):25377-25381.
APA	Xue, Feng,Liu, Qibin,Zhu, Yong,Qing, Yunfei,&Wan, Boshun.(2019).Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines.RSC ADVANCES,9(44),25377-25381.
MLA	Xue, Feng,et al."Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines".RSC ADVANCES 9.44(2019):25377-25381.