Active Species in Photocatalytic Reactions of Methanol on TiO2(110) Identified by Surface Sum Frequency Generation Vibrational Spectroscopy | |
Peng XX; Zhang RD; Feng RR(冯冉冉); Liu AA; Zhou CY; Guo Q; Yang XM; Jiang Y; Ren ZF | |
刊名 | JOURNAL OF PHYSICAL CHEMISTRY C |
2019-06-06 | |
卷号 | 123期号:22页码:13789-13794 |
ISSN号 | 1932-7447 |
DOI | 10.1021/acs.jpcc.9b03922 |
通讯作者 | Ren, Zefeng(zfren@dicp.ac.cn) |
英文摘要 | The photocatalytic reactivity of one monolayer of methanol on TiO2(110) was measured with the surface sum frequency generation vibrational spectroscopy in the C-H stretching range, which shows high photon energy dependence. The photocatalytic reactivity was systematically investigated for different active species on TiO2(110), dissociative adsorbed methanol at five-coordinated Ti sites (Ti-5c), methoxy without adsorbed methanol at Ti-5c sites, and methoxy O-b sites. The results show that the methoxy at Ti-5c sites has much higher photocatalytic reactivity than that of dissociative adsorbed methanol at Ti-5c sites, and the methoxy at O-b sites might be inactive. This work demonstrates that methoxy at Ti-5c sites is the most active species on TiO2(110) and suggests that effectively removing surface OH could enhance the photodegradation of surface organics. |
分类号 | 二类/Q1 |
资助项目 | Ministry of Science and Technology of China[2018YFA0208700] ; Ministry of Science and Technology of China[2016YFA0200602] ; Chinese Academy of Sciences[XDB17000000] ; National Natural Science Foundation of China[91645125] ; National Natural Science Foundation of China[21688102] ; Youth Innovation Promotion Association of CAS[2017224] |
WOS关键词 | METHYL FORMATE ; DEFECTIVE TIO2(110) ; HYDROGEN-PRODUCTION ; ALIPHATIC-ALCOHOLS ; RUTILE TIO2(110) ; TIO2 110 ; WATER ; DISSOCIATION ; ADSORPTION ; FORMALDEHYDE |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
语种 | 英语 |
WOS记录号 | WOS:000470938400049 |
资助机构 | Ministry of Science and Technology of China ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; Youth Innovation Promotion Association of CAS |
其他责任者 | Ren, Zefeng |
内容类型 | 期刊论文 |
源URL | [http://dspace.imech.ac.cn/handle/311007/79349] |
专题 | 力学研究所_国家微重力实验室 |
推荐引用方式 GB/T 7714 | Peng XX,Zhang RD,Feng RR,et al. Active Species in Photocatalytic Reactions of Methanol on TiO2(110) Identified by Surface Sum Frequency Generation Vibrational Spectroscopy[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2019,123(22):13789-13794. |
APA | Peng XX.,Zhang RD.,冯冉冉.,Liu AA.,Zhou CY.,...&Ren ZF.(2019).Active Species in Photocatalytic Reactions of Methanol on TiO2(110) Identified by Surface Sum Frequency Generation Vibrational Spectroscopy.JOURNAL OF PHYSICAL CHEMISTRY C,123(22),13789-13794. |
MLA | Peng XX,et al."Active Species in Photocatalytic Reactions of Methanol on TiO2(110) Identified by Surface Sum Frequency Generation Vibrational Spectroscopy".JOURNAL OF PHYSICAL CHEMISTRY C 123.22(2019):13789-13794. |
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