Stereoselective synthesis of (+/-)-tacamonine

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	Stereoselective synthesis of (+/-)-tacamonine
	He ZL(何子乐) ; Lin QX(林其先)
刊名	Tetrahedron
	2008
卷号	64 期号:45 页码:10401-10405
ISSN号	0040-4020
其他题名	Stereoselective synthesis of (+/-)tacamonine
通讯作者	何子乐
英文摘要	We report a stereocontrolled approach to the pentacyclic indole alkaloid tacamonine by modifying an earlier route using norbornadiene to supply the nontryptamine portion. By maintaining a bridged system the reduction step of the Bischler-Napieralski reaction proceeded to deliver a bridged diol in which three methine hydrogen atoms are in an all-cis configuration. All 19 skeletal carbon atoms are fully incorporated, therefore, the only remaining steps involved cleavage of the vic-diol subunit in the seven-membered ring and further oxidation and reduction of the resulting lactam alclehyde. (C) 2008 Elsevier Ltd. All rights reserved.
学科主题	天然产物有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.tet.2008.08.049
语种	英语
WOS记录号	WOS:000260290900013
公开日期	2013-08-14
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/27703]
专题	上海有机化学研究所_上海有机化学研究所
推荐引用方式 GB/T 7714	He ZL,Lin QX. Stereoselective synthesis of (+/-)-tacamonine[J]. Tetrahedron,2008,64(45):10401-10405.
APA	何子乐,&林其先.(2008).Stereoselective synthesis of (+/-)-tacamonine.Tetrahedron,64(45),10401-10405.
MLA	何子乐,et al."Stereoselective synthesis of (+/-)-tacamonine".Tetrahedron 64.45(2008):10401-10405.