Syntheses, structures, photoluminescence, and magnetic properties of (3,6)-and 4-connected lanthanide metal-organic frameworks with a semirigid tricarboxylate ligand

	Syntheses, structures, photoluminescence, and magnetic properties of (3,6)-and 4-connected lanthanide metal-organic frameworks with a semirigid tricarboxylate ligand
	Su SQ ; Wang S ; Song XZ ; Song SY ; Qin C ; Zhu M ; Hao ZM ; Zhao SN ; Zhang HJ
刊名	dalton transactions
	2012
卷号	41 期号:16 页码:4772-4779
关键词	EARTH COORDINATION POLYMERS CRYSTAL-STRUCTURE LUMINESCENT PROPERTIES SORPTION PROPERTIES BUILDING UNITS GADOLINIUM CARBOXYLATES GAS-ADSORPTION COMPLEXES ACID IONS
ISSN号	1477-9226
通讯作者	zhang hj
中文摘要	lanthanide coordination polymers [lnl(dmf)(2)]center dot 0.25h(2)o [ln = la (1), ce (2), pr (3), nd (4), sm (5), eu (6), gd (7), tb (8), dy (9), ho (10), er (11), and tm (12)], and [gdl(h2o)(3)] (7') (h3l = 5-(4-carboxy-2-nitrophenoxy)-isophthalic acid), have been synthesized under hydro-and solvothermal conditions, respectively. compounds 1-12 exhibit the same three-dimensional (3d) architecture, which is built up from binuclear paddle-wheel building blocks, and their resulting frameworks can be rationalized as rarely reported flu-3,6-c2/c topology. compound 7' crystallizes in the monoclinic system, space group p2(1)/c. the ligands (l) bridge the gd(iii) centers to form 3d frameworks featuring a zeolite bct topology, which have been unreported based on rare earth metals until now. moreover, compound 6 exhibits characteristic red luminescent properties of eu(iii) complexes. the magnetic susceptibilities, over a temperature range of 2.0-300 k, of 7 and 7' have also been investigated.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000302023800010
公开日期	2013-06-30
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/48610]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Su SQ,Wang S,Song XZ,et al. Syntheses, structures, photoluminescence, and magnetic properties of (3,6)-and 4-connected lanthanide metal-organic frameworks with a semirigid tricarboxylate ligand[J]. dalton transactions,2012,41(16):4772-4779.
APA	Su SQ.,Wang S.,Song XZ.,Song SY.,Qin C.,...&Zhang HJ.(2012).Syntheses, structures, photoluminescence, and magnetic properties of (3,6)-and 4-connected lanthanide metal-organic frameworks with a semirigid tricarboxylate ligand.dalton transactions,41(16),4772-4779.
MLA	Su SQ,et al."Syntheses, structures, photoluminescence, and magnetic properties of (3,6)-and 4-connected lanthanide metal-organic frameworks with a semirigid tricarboxylate ligand".dalton transactions 41.16(2012):4772-4779.