Hydrothermal Derived LaOF:Ln(3+) (Ln = Eu, Tb, Sm, Dy, Tm, and/or Ho) Nanocrystals with Multicolor-Tunable Emission Properties | |
Shang MM ; Geng DL ; Kang XJ ; Yang DM ; Zhang Y ; Lin J | |
刊名 | inorganic chemistry
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2012 | |
卷号 | 51期号:20页码:11106-11116 |
关键词 | LIGHT-EMITTING-DIODES ENERGY-TRANSFER THIN-FILMS LUMINESCENCE PROPERTIES PROMISING PHOSPHORS DISPLAYS PHOTOLUMINESCENCE WHITE CATHODOLUMINESCENCE NANOTUBES |
ISSN号 | 0020-1669 |
通讯作者 | lin j |
中文摘要 | a series of laof:ln(3+) (ln = eu, tb, sm, dy, tm, and/or ho) nanocrystals with good dispersion have been successfully prepared by the hydrothermal method followed a heat-treatment process. under ultraviolet radiation and low-voltage electron beam excitation, the laof:ln(3+) nanocrystals show the characteristic f-f emissions of ln(3+) (ln = eu, tb, sm, dy, tm, or ho) and give red, blue-green, orange, yellow, blue, and green emission, respectively. moreover, there exists simultaneous luminescence of tb3+, eu3+, sm3+, dy3+, tm3+, or ho3+ individually when codoping them in the single-phase laof host (for example, laof:tb3+, eu3+/sm3+; laof:tm3+, dy3+/ho3+; laof:tm3+, ho3+, eu3+ systems), which is beneficial to tune the emission colors. under low-voltage electron beam excitation, a variety of colors can be efficiently adjusted by varying the doping ions and the doping concentration, making these materials have potential applications in field-emission display devices. more importantly, the energy transfer from tm3+ to ho3+ in the laof:tm3+, ho3+ samples under uv excitation was first investigated and has been demonstrated to be a resonant type via a quadrupole-quadrupole mechanism. the critical distance (rtm-ho) is calculated to be 28.4 angstrom. in addition, the laof:tb3+ and laof:tm3+ phosphors exhibit green and blue luminescence with better chromaticity coordinates, color purity, and higher intensity compared with the commercial green phosphor zno:zn and blue phosphor y2sio5:ce3+ to some extent under low-voltage electron beam excitation. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000309739100066 |
公开日期 | 2013-04-22 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/47898] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Shang MM,Geng DL,Kang XJ,et al. Hydrothermal Derived LaOF:Ln(3+) (Ln = Eu, Tb, Sm, Dy, Tm, and/or Ho) Nanocrystals with Multicolor-Tunable Emission Properties[J]. inorganic chemistry,2012,51(20):11106-11116. |
APA | Shang MM,Geng DL,Kang XJ,Yang DM,Zhang Y,&Lin J.(2012).Hydrothermal Derived LaOF:Ln(3+) (Ln = Eu, Tb, Sm, Dy, Tm, and/or Ho) Nanocrystals with Multicolor-Tunable Emission Properties.inorganic chemistry,51(20),11106-11116. |
MLA | Shang MM,et al."Hydrothermal Derived LaOF:Ln(3+) (Ln = Eu, Tb, Sm, Dy, Tm, and/or Ho) Nanocrystals with Multicolor-Tunable Emission Properties".inorganic chemistry 51.20(2012):11106-11116. |
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