New organically ternplated copper(I) sulfites: the role of sulfite anion as both soft and hard ligand

	New organically ternplated copper(I) sulfites: the role of sulfite anion as both soft and hard ligand
	P. X. Li ; H. L. Jiang ; M. L. Fengt ; J. G. Mao
刊名	Inorganic Chemistry
	2007-10
卷号	46 期号:20 页码:8302-8308
关键词	crystal-structure structural-characterization different dimensionalities metal phosphates complexes selenites clusters series ta5+ nb5+
ISSN号	0020-1669
中文摘要	Two new organically templated layered copper(l) sulfites, namely, {H(2)PiP}{Cu-3(CN)(3)(SO3)}(1) and {H(2)PiP}- NaCu2(SO3)2Br(H2O)center dot 2H(2)O (2) (pip = piperazine), have been synthesized by hydrothermal reactions of copper(1) cyanide or copper(l) bromide with NaHSO3 and piperazine. Both compounds exhibit a layered structure. The 2D layer of { Cu-3(CN)(3)(SO3)(2-) in 1 is composed of 1 D chains of copper(l) cyanide interconnected by sulfite anions via both Cu-S and Cu-O bonds, whereas the 2D layer of {NaCu2(SO3)(2)Br2- in 2 is formed by 1D chains of copper(l) bromide and 1D sodium(l) aqua chains that are interconnected by sulfite anions via Na-O, Cu-S, and Cu-O bonds. Chemical bonding in 1 and 2 has been also investigated by theoretical calculations based on DFT methods.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6398]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	P. X. Li,H. L. Jiang,M. L. Fengt,et al. New organically ternplated copper(I) sulfites: the role of sulfite anion as both soft and hard ligand[J]. Inorganic Chemistry,2007,46(20):8302-8308.
APA	P. X. Li,H. L. Jiang,M. L. Fengt,&J. G. Mao.(2007).New organically ternplated copper(I) sulfites: the role of sulfite anion as both soft and hard ligand.Inorganic Chemistry,46(20),8302-8308.
MLA	P. X. Li,et al."New organically ternplated copper(I) sulfites: the role of sulfite anion as both soft and hard ligand".Inorganic Chemistry 46.20(2007):8302-8308.