Synthesis and characterization of organically templated copper halides with zero and one-dimensional hybrid structures: (nbq)(4)Cu4I8 and (ipq)(2)(Cu5I7) (n)

	Synthesis and characterization of organically templated copper halides with zero and one-dimensional hybrid structures: (nbq)(4)Cu4I8 and (ipq)(2)(Cu5I7) (n)
	H. H. Li ; Z. R. Chen ; Y. Liu ; K. N. Ding ; J. Q. Li ; C. C. Huang ; L. Q. Guo
刊名	Journal of Cluster Science
	2007-12
卷号	18 期号:4 页码:817-829
关键词	coordination polymers organic-inorganic hybrid copper iodide cyclic voltammetry hydrothermal synthesis crystal-structure tetranuclear clusters cui br cl
ISSN号	1040-7278
中文摘要	Two new organically templated copper halides, (nbq)(4)Cu4I8 (1) and [(ipq)(2) (Cu5I7)](n) (2) have been synthesized in the presence of nbq(+) and ibq(+) (nbq(+) = N-(n-butyl)-quinolinium, ibq(+) = N-(iso-pentyl)-quinolinium) acting as structure-directing agents(SDAs). Both of the compounds present hybrid structures with SDAs and inorganic moieties being incorporated. In 1, tetrameric Cu4I84- anion is composed by edge-sharing CuI4 tetrahedrons and CuI3 planar triangles. But the inorganic framework of 2 presents one-dimensional arrangement which results from the tetrahedron CuI4 and pseudo trigonal pyramid CuI3 through edge-sharing fashion. Electrostatic interactions between organic counter cations and inorganic moieties could be observed and contribute to the crystal packing. Both compounds are further characterized by IR, UV - Vis, elemental analysis, fluorescence and cyclic voltammetry.
语种	英语
公开日期	2013-04-01
内容类型	期刊论文
源URL	[http://ir.fjirsm.ac.cn/handle/350002/6385]
专题	福建物质结构研究所_中科院福建物质结构研究所_期刊论文
推荐引用方式 GB/T 7714	H. H. Li,Z. R. Chen,Y. Liu,et al. Synthesis and characterization of organically templated copper halides with zero and one-dimensional hybrid structures: (nbq)(4)Cu4I8 and (ipq)(2)(Cu5I7) (n)[J]. Journal of Cluster Science,2007,18(4):817-829.
APA	H. H. Li.,Z. R. Chen.,Y. Liu.,K. N. Ding.,J. Q. Li.,...&L. Q. Guo.(2007).Synthesis and characterization of organically templated copper halides with zero and one-dimensional hybrid structures: (nbq)(4)Cu4I8 and (ipq)(2)(Cu5I7) (n).Journal of Cluster Science,18(4),817-829.
MLA	H. H. Li,et al."Synthesis and characterization of organically templated copper halides with zero and one-dimensional hybrid structures: (nbq)(4)Cu4I8 and (ipq)(2)(Cu5I7) (n)".Journal of Cluster Science 18.4(2007):817-829.