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	A novel Suzuki-type cross-coupling reaction of cyclopropylboronic esters with benzyl bromides
	Chen H(陈寒) ; Deng MZ(邓敏智)
刊名	J. Chem. Soc.-Perkin Trans. 1
	2000
期号	10页码:1609-1613
ISSN号	1472-7781
其他题名	一个新奇的环丙基硼酸酯与苄溴的Suzuki类型交叉偶亮反应
通讯作者	邓敏智
英文摘要	The Suzuki-type coupling reaction of cyclopropylboronic acids (esters) with benzyl bromides readily takes place by using Ag^2O with KOH as the base. The reaction rate and the cross-coupling product yields of cyclopropylbbroMte esters of ethylene glycol or propane-1,3-diol were higher and better than those of cyclopropylfloronic acids. However, the cohpling reaction of the cyclopropylboronate esters of glycol with larger substituents was sluggish. The highly optically active benzyl-substituted cyclopropanes could be obtained by the coupling reactions of corrp.ppnding optically active cyclopropylboronate esters with benzyl bromides. A novel, ideal method fat preparing stereo-defined benzyl-substituted cyclopropanes, especially optically active benryl-substituted cyclopropanes, is described here.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1039/b000121j
语种	英语
WOS记录号	WOS:000087318600019
公开日期	2013-03-07
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/23086]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Chen H,Deng MZ. A novel Suzuki-type cross-coupling reaction of cyclopropylboronic esters with benzyl bromides[J]. J. Chem. Soc.-Perkin Trans. 1,2000(10):1609-1613.
APA	陈寒,&邓敏智.(2000).A novel Suzuki-type cross-coupling reaction of cyclopropylboronic esters with benzyl bromides.J. Chem. Soc.-Perkin Trans. 1(10),1609-1613.
MLA	陈寒,et al."A novel Suzuki-type cross-coupling reaction of cyclopropylboronic esters with benzyl bromides".J. Chem. Soc.-Perkin Trans. 1 .10(2000):1609-1613.

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