Total Synthesis of (+/-)-Spiniferin-1 via a Polyfluoroalkanosulfonyl Fluoride Induced Homoallylic Carbocation Rearrangement Reaction

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	Total Synthesis of (+/-)-Spiniferin-1 via a Polyfluoroalkanosulfonyl Fluoride Induced Homoallylic Carbocation Rearrangement Reaction
	Ding K(丁凯) ; Sun YS(孙云山) ; Tian WS(田伟生)
刊名	J. Org. Chem.
	2011
卷号	76 期号:5 页码:1495-1498
ISSN号	0022-3263
其他题名	(±)-Spiniferin-1的全合成
通讯作者	田伟生
英文摘要	A facile total synthesis of marine natural product (+/-)-spiniferin-1 has been accomplished in eight steps with 28.9% overall yield, involving a rearrangement reaction initiated by polyfluoroalkanosulfonyl fluoride to construct the 1,6-methano[10]annulene core of the natural product as a key step.
学科主题	天然产物有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/jo102351k
语种	英语
WOS记录号	WOS:000287636200039
公开日期	2013-03-11
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/23880]
专题	上海有机化学研究所_中科院天然产物有机化学重点实验室
推荐引用方式 GB/T 7714	Ding K,Sun YS,Tian WS. Total Synthesis of (+/-)-Spiniferin-1 via a Polyfluoroalkanosulfonyl Fluoride Induced Homoallylic Carbocation Rearrangement Reaction[J]. J. Org. Chem.,2011,76(5):1495-1498.
APA	丁凯,孙云山,&田伟生.(2011).Total Synthesis of (+/-)-Spiniferin-1 via a Polyfluoroalkanosulfonyl Fluoride Induced Homoallylic Carbocation Rearrangement Reaction.J. Org. Chem.,76(5),1495-1498.
MLA	丁凯,et al."Total Synthesis of (+/-)-Spiniferin-1 via a Polyfluoroalkanosulfonyl Fluoride Induced Homoallylic Carbocation Rearrangement Reaction".J. Org. Chem. 76.5(2011):1495-1498.