Development of a General and Practical Iron Nitrate/TEMPO-Catalyzed Aerobic Oxidation of Alcohols to Aldehydes/Ketones: Catalysis with Table Salt

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	Development of a General and Practical Iron Nitrate/TEMPO-Catalyzed Aerobic Oxidation of Alcohols to Aldehydes/Ketones: Catalysis with Table Salt
	Ma SM(麻生明) ; Liu JX(刘金仙) ; Li SH(李苏华) ; Chen B(陈波) ; Cheng JJ(成佳佳) ; Kuang JQ(况锦强) ; Liu Y(刘宇) ; Wan BQ(万保强) ; Wang YL(王玉立) ; Ye JT(叶俊涛) ; Yu Q(俞琼) ; Yuan WM(袁伟明) ; Yu SC(余世超)
刊名	Adv. Synth. Catal.
	2011
卷号	353 期号:6 页码:1005-1017
ISSN号	1615-4150
其他题名	发展一种通用、易操作的硝酸铁、TEMPO和食盐共催化的醇到醛/酮的空气氧化反应
通讯作者	麻生明
英文摘要	Oxidation of alcohols is a fundamental transformation related to our daily life. Traditional approaches with at least one stoichiometric amount of oxidants are expensive and cause serious environmental burdens. There are many reports on the aerobic oxidation of simple alcohols such as alkyl or phenyl carbinols and allylic alcohols, which used oxygen or air as the environmentally benign oxidant forming water as the only by-product. However, no such protocol has been reported for allenols and propargylic alcohols. Thus, it still highly desirable to develop efficient room temperature oxidations of alcohols with a wide scope including allenols and propargylic alcohols. In this paper, an efficient and clean aerobic oxidation of so far the widest spectrum of alcohols using 1 atm of oxygen or air, producing aldehydes/ketones at room temperature in fairly high isolated yields mostly within a couple of hours is described. It is interesting to observe that the reaction has been efficiently expedited by a catalytic amount of sodium chloride in easily recoverable 1,2-dichloroethane. A mechanism involving NO and NO(2) has been proposed based on the results of the control experiments and GC-MS studies of the in-situ formed gas phase of the reaction mixture.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/adsc.201100033
语种	英语
WOS记录号	WOS:000290613800028
公开日期	2013-01-16
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/12234]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Ma SM,Liu JX,Li SH,et al. Development of a General and Practical Iron Nitrate/TEMPO-Catalyzed Aerobic Oxidation of Alcohols to Aldehydes/Ketones: Catalysis with Table Salt[J]. Adv. Synth. Catal.,2011,353(6):1005-1017.
APA	麻生明.,刘金仙.,李苏华.,陈波.,成佳佳.,...&余世超.(2011).Development of a General and Practical Iron Nitrate/TEMPO-Catalyzed Aerobic Oxidation of Alcohols to Aldehydes/Ketones: Catalysis with Table Salt.Adv. Synth. Catal.,353(6),1005-1017.
MLA	麻生明,et al."Development of a General and Practical Iron Nitrate/TEMPO-Catalyzed Aerobic Oxidation of Alcohols to Aldehydes/Ketones: Catalysis with Table Salt".Adv. Synth. Catal. 353.6(2011):1005-1017.