Study on the reactions of fluoroalkanesulfonyl azides with pyrazine and its derivatives

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	Study on the reactions of fluoroalkanesulfonyl azides with pyrazine and its derivatives
	Xiong WT(熊婉婷) ; Zhang HF(张洪飞) ; Xin Y(信勇) ; Zhu SZ(朱仕正)
刊名	Tetrahedron
	2011
卷号	67 期号:12 页码:2232-2237
ISSN号	0040-4020
其他题名	氟烷基磺酰叠氮与吡嗪及其衍生物的反应研究
通讯作者	朱仕正
英文摘要	The thermal reactions of fluoroalkanesulfonyl azides RfSO2N3 with pyrazine and its derivatives are studied in detail. All the reactions involved the fluoroalkanesulfonyl nitrene intermediates RfSO3N: which was captured by pyrazine to give the pyrazinium N-fluoroalkanesulfonyl ylides C4NH4N+- -NSO2Rf and hydrogen abstraction product RfSO2NH2, but no corresponding N-pyrazinyl fluoroalkanesulfonyl amide derivatives RfSO2NHC4N2H3 were isolated. Excess azides did not afford the bisN-ylide product RfSO2N--+NC4H4N+--NSO2Rf. (C) 2011 Elsevier Ltd. All rights reserved.
学科主题	有机氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.tet.2011.01.077
语种	英语
WOS记录号	WOS:000288778100006
公开日期	2013-01-18
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/14502]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Xiong WT,Zhang HF,Xin Y,et al. Study on the reactions of fluoroalkanesulfonyl azides with pyrazine and its derivatives[J]. Tetrahedron,2011,67(12):2232-2237.
APA	熊婉婷,张洪飞,信勇,&朱仕正.(2011).Study on the reactions of fluoroalkanesulfonyl azides with pyrazine and its derivatives.Tetrahedron,67(12),2232-2237.
MLA	熊婉婷,et al."Study on the reactions of fluoroalkanesulfonyl azides with pyrazine and its derivatives".Tetrahedron 67.12(2011):2232-2237.