A new entry to asymmetric synthesis of optically active alpha,gamma-substituted gamma-butyrolactones, using a carbohydrate derived amide as both a chiral auxiliary and a proton source

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	A new entry to asymmetric synthesis of optically active alpha,gamma-substituted gamma-butyrolactones, using a carbohydrate derived amide as both a chiral auxiliary and a proton source
	Huang LL(黄凌琳) ; Xu MH(徐明华) ; Lin GQ(林国强)
刊名	J. Org. Chem.
	2005
卷号	70 期号:2 页码:529-532
ISSN号	0022-3263
其他题名	不对称合成光学活性α,γ-取代-γ-丁内酯的新方法：从糖衍生的酰胺类化合物同时作为手性辅剂和质子源
通讯作者	徐明华
英文摘要	DIAGRAM A new entry for the asymmetric synthesis of optically active alpha,gamma-substituted gamma-butyrolactones was developed by using a carbohydrate-derived amide as both a chiral auxiliary and a proton source. Unlike the previously reported examples, the chiral auxiliary, employed in this reaction also successfully functioned as a protonating agent. Excellent asymmetric induction could be achieved by this dual stereoselective control in the reaction process.
学科主题	生命有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/jo0485637
语种	英语
WOS记录号	WOS:000226313600019
公开日期	2013-02-20
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/16645]
专题	上海有机化学研究所_中科院天然产物有机化学重点实验室
推荐引用方式 GB/T 7714	Huang LL,Xu MH,Lin GQ. A new entry to asymmetric synthesis of optically active alpha,gamma-substituted gamma-butyrolactones, using a carbohydrate derived amide as both a chiral auxiliary and a proton source[J]. J. Org. Chem.,2005,70(2):529-532.
APA	黄凌琳,徐明华,&林国强.(2005).A new entry to asymmetric synthesis of optically active alpha,gamma-substituted gamma-butyrolactones, using a carbohydrate derived amide as both a chiral auxiliary and a proton source.J. Org. Chem.,70(2),529-532.
MLA	黄凌琳,et al."A new entry to asymmetric synthesis of optically active alpha,gamma-substituted gamma-butyrolactones, using a carbohydrate derived amide as both a chiral auxiliary and a proton source".J. Org. Chem. 70.2(2005):529-532.