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A Silver Nanocluster Containing Interstitial Sulfur and Unprecedented Chemical Bonds
Liu, Xu4,5,6; Chen, Jishi6; Yuan, Jinyun3; Li, Yizhi2; Li, Jin1; Zhou, Shiming3; Yao, Chuanhao6; Liao, Lingwen6; Zhuang, Shengli4,5,6; Zhao, Yan4,5,6
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2018-08-27
卷号57期号:35页码:11273-11277
关键词interstitial sulfur nanoclusters photoluminescence silver structure
ISSN号1433-7851
DOI10.1002/anie.201805594
通讯作者Yang, Jinlong(jlyang@ustc.edu.cn) ; Wu, Zhikun(zkwu@issp.ac.cn)
英文摘要The emergence of thiolated metal nanoclusters provides opportunities to identify significant and unprecedented phenomena because they are at quantum sizes and can be characterized with X-ray crystallography. Recently silver nanoclusters have received extensive interest owing to their merits, such as low-cost and rich properties. Herein, a thiolated silver nanocluster [Ag46S7(SPhMe2)(24)]NO3 (Ag-46 for short) with a face-centered cubic (fcc) structure was successfully synthesized and structurally resolved by X-ray analysis. Most importantly, interstitial sulfur was found in the lattice void of Ag-46 without lattice distortion or expansion, indicating that the classic theory of interstitial metal solid solutions might be not applicable at quantum size. Furthermore, unprecedented chemical bonds and unique structural features (such as asymmetrically coordinated mu(4)-S) were found in Ag-46 and might be related to the interstitial sulfur, which is supported by natural population analyses.
资助项目National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21688102] ; National Natural Science Foundation of China[21601193] ; National Natural Science Foundation of China[21603234] ; National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[21528303] ; National Key Research & Development Program of China[2016YFA0200604] ; Key Program of 13th five-year plan ; CASHIPS[KP-2017-16] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2017FXCX002] ; CAS/SAFEA International Partnership Program for Creative Research Teams
WOS关键词PROTECTED GOLD CLUSTERS ; THEORETICAL-ANALYSIS ; CRYSTAL-STRUCTURE ; SOLID-SOLUTIONS ; NANOPARTICLES ; ATOMS ; RESOLUTION ; COMPLEXES ; AU-25
WOS研究方向Chemistry
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000442340000026
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; 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内容类型期刊论文
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/38609]  
专题合肥物质科学研究院_中科院固体物理研究所
通讯作者Yang, Jinlong; Wu, Zhikun
作者单位1.Tsinghua Univ, Sch Life Sci, Tsinghua Univ Peking Univ Joint Ctr Life Sci, Beijing 100084, Peoples R China
2.Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
3.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
4.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China
5.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China
6.Chinese Acad Sci, Inst Solid State Phys, CAS Ctr Excellence Nanosci, Key Lab Mat Phys,Anhui Key Lab Nanomat & Nanotech, Hefei 230031, Anhui, Peoples R China
推荐引用方式
GB/T 7714		 Liu, Xu,Chen, Jishi,Yuan, Jinyun,et al. A Silver Nanocluster Containing Interstitial Sulfur and Unprecedented Chemical Bonds[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(35):11273-11277.
APA Liu, Xu.,Chen, Jishi.,Yuan, Jinyun.,Li, Yizhi.,Li, Jin.,...&Wu, Zhikun.(2018).A Silver Nanocluster Containing Interstitial Sulfur and Unprecedented Chemical Bonds.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(35),11273-11277.
MLA Liu, Xu,et al."A Silver Nanocluster Containing Interstitial Sulfur and Unprecedented Chemical Bonds".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.35(2018):11273-11277.
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